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author:

Liu, Yanru (Liu, Yanru.) [1] | Lei, Zewei (Lei, Zewei.) [2] | Li, Xinye (Li, Xinye.) [3] | Lin, Chuyuan (Lin, Chuyuan.) [4] | Liu, Renpin (Liu, Renpin.) [5] | Cao, Changlin (Cao, Changlin.) [6] | Chen, Qinghua (Chen, Qinghua.) [7] | Wei, Mingdeng (Wei, Mingdeng.) [8] | Zeng, Lingxing (Zeng, Lingxing.) [9] | Qian, Qingrong (Qian, Qingrong.) [10]

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EI

Abstract:

Metal 1T phase molybdenum disulfide (1T-MoS2) is being actively considered as a promising anode due to its high conductivity, which can improve electron transfer. Herein, we elaborately designed stable Sb-doped metallic 1T phase molybdenum sulfide (1T-MoS2-Sb) with a few-layered nanosheet structure via a simple calcination technique. The N-doping of the carbon and Sb-doping induce the formation of T-phase MoS2, which not only effectively enhances the entire stability of the structure, but also improves its cycling performance and stability. When employed as an anode of sodium-ion batteries (SIBs), 1T-MoS2-Sb exhibits a reversible capacity of 493 mA h g−1 at 0.1 A g−1 after 100 cycles and delivers prominent long-term performance (253 mA h g−1 at 1 A g−1 after 2200 cycles) along with decent rate capability. Paired with a Na3V2(PO4)3 cathode, it displays a superior capacity of 242 mA h g−1 at 0.5 A g−1 over 100 cycles, which is one of the best performances of a MoS2-based full cell for SIBs. Employed as the anode for potassium-ion batteries (PIBs), it exhibits a satisfactory specific capacity of 343 mA h g−1 at 0.1 A g−1 after 100 cycles. This facile strategy will provide new insights for designing T-phase advanced anode materials for SIBs/PIBs. © 2022 The Royal Society of Chemistry.

Keyword:

Anodes Carbon Carbon disulfide Doping (additives) Layered semiconductors Metal ions Molybdenum disulfide Nanosheets Sodium compounds Sodium-ion batteries

Community:

  • [ 1 ] [Liu, Yanru]College of Life Science, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 2 ] [Lei, Zewei]College of Life Science, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 3 ] [Lei, Zewei]Engineering Research Center of Polymer Green Recycling of Ministry of Education, College of Environmental Science and Engineering, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 4 ] [Li, Xinye]Engineering Research Center of Polymer Green Recycling of Ministry of Education, College of Environmental Science and Engineering, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 5 ] [Li, Xinye]Fujian Key Laboratory of Pollution Control & Resource Reuse, Fujian, Fuzhou; 350007, China
  • [ 6 ] [Lin, Chuyuan]Engineering Research Center of Polymer Green Recycling of Ministry of Education, College of Environmental Science and Engineering, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 7 ] [Lin, Chuyuan]Fujian Key Laboratory of Pollution Control & Resource Reuse, Fujian, Fuzhou; 350007, China
  • [ 8 ] [Liu, Renpin]Engineering Research Center of Polymer Green Recycling of Ministry of Education, College of Environmental Science and Engineering, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 9 ] [Liu, Renpin]Fujian Key Laboratory of Pollution Control & Resource Reuse, Fujian, Fuzhou; 350007, China
  • [ 10 ] [Cao, Changlin]Engineering Research Center of Polymer Green Recycling of Ministry of Education, College of Environmental Science and Engineering, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 11 ] [Cao, Changlin]Fujian Key Laboratory of Pollution Control & Resource Reuse, Fujian, Fuzhou; 350007, China
  • [ 12 ] [Chen, Qinghua]Engineering Research Center of Polymer Green Recycling of Ministry of Education, College of Environmental Science and Engineering, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 13 ] [Chen, Qinghua]Fujian Key Laboratory of Pollution Control & Resource Reuse, Fujian, Fuzhou; 350007, China
  • [ 14 ] [Wei, Mingdeng]Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, Fuzhou University, Fujian, Fuzhou; 350002, China
  • [ 15 ] [Zeng, Lingxing]Engineering Research Center of Polymer Green Recycling of Ministry of Education, College of Environmental Science and Engineering, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 16 ] [Zeng, Lingxing]Fujian Key Laboratory of Pollution Control & Resource Reuse, Fujian, Fuzhou; 350007, China
  • [ 17 ] [Zeng, Lingxing]Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin; 300071, China
  • [ 18 ] [Qian, Qingrong]Engineering Research Center of Polymer Green Recycling of Ministry of Education, College of Environmental Science and Engineering, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 19 ] [Qian, Qingrong]Fujian Key Laboratory of Pollution Control & Resource Reuse, Fujian, Fuzhou; 350007, China
  • [ 20 ] [Qian, Qingrong]Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin; 300071, China

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Source :

Dalton Transactions

ISSN: 1477-9226

Year: 2022

Issue: 31

Volume: 51

Page: 11685-11692

4 . 0

JCR@2022

3 . 5 0 0

JCR@2023

ESI HC Threshold:74

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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