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Abstract:
The hydrogenation of petroleum resin(PR)is an effective process to prepare high value-added hydro-genated PR(HPR).However,the preparation of non-noble metal-based catalysts with high catalytic activ-ity for PR hydrogenation still remains a challenge.Herein,a La promoted Ni-based catalyst is reported through the thermal reduction of quaternary NiLaMgAl-layered double hydroxides(NiLaMgAl-LDHs).The incorporation of La is beneficial to the reduction and stability of Ni particles with reduced particle size,and the increased alkalinity effectively mitigates the breakage of molecular chains of PR.As a result,the La promoted Ni-based catalyst exhibits high catalytic activity and excellent stability for PR hydro-genation.A hydrogenation degree of 95.4%and 96.1%can be achieved for HC5PR and HC9PR with less reduced softening point,respectively.Notably,the hydrogenation degree still maintains at 92.7%even after 100 hours'reaction,much better than that without La incorporation or prepared using conventional impregnation method.
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中国化学工程学报(英文版)
ISSN: 1004-9541
CN: 11-3270/TQ
Year: 2022
Issue: 5
Volume: 45
Page: 41-50
3 . 8
JCR@2022
3 . 7 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:74
JCR Journal Grade:2
CAS Journal Grade:2
Cited Count:
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count: -1
Chinese Cited Count:
30 Days PV: 1
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