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author:

Qunhong Liu (Qunhong Liu.) [1] | Jiangtao Yang (Jiangtao Yang.) [2] | Hongwei Zhang (Hongwei Zhang.) [3] (Scholars:张宏伟) | Hongming Sun (Hongming Sun.) [4] | Shuzheng Wu (Shuzheng Wu.) [5] | Bingqing Ge (Bingqing Ge.) [6] | Rong Wang (Rong Wang.) [7] | Pei Yuan (Pei Yuan.) [8] (Scholars:袁珮)

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Abstract:

The hydrogenation of petroleum resin(PR)is an effective process to prepare high value-added hydro-genated PR(HPR).However,the preparation of non-noble metal-based catalysts with high catalytic activ-ity for PR hydrogenation still remains a challenge.Herein,a La promoted Ni-based catalyst is reported through the thermal reduction of quaternary NiLaMgAl-layered double hydroxides(NiLaMgAl-LDHs).The incorporation of La is beneficial to the reduction and stability of Ni particles with reduced particle size,and the increased alkalinity effectively mitigates the breakage of molecular chains of PR.As a result,the La promoted Ni-based catalyst exhibits high catalytic activity and excellent stability for PR hydro-genation.A hydrogenation degree of 95.4%and 96.1%can be achieved for HC5PR and HC9PR with less reduced softening point,respectively.Notably,the hydrogenation degree still maintains at 92.7%even after 100 hours'reaction,much better than that without La incorporation or prepared using conventional impregnation method.

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Community:

  • [ 1 ] [Shuzheng Wu]Research Center of Chemical Fertilizer Catalyst,Fuzhou University,Fuzhou 350002,China
  • [ 2 ] [Bingqing Ge]Research Center of Chemical Fertilizer Catalyst,Fuzhou University,Fuzhou 350002,China
  • [ 3 ] [Pei Yuan]Research Center of Chemical Fertilizer Catalyst,Fuzhou University,Fuzhou 350002,China
  • [ 4 ] [Hongwei Zhang]福州大学
  • [ 5 ] [Rong Wang]福州大学
  • [ 6 ] [Jiangtao Yang]福州大学
  • [ 7 ] [Qunhong Liu]Research Center of Chemical Fertilizer Catalyst,Fuzhou University,Fuzhou 350002,China
  • [ 8 ] [Hongming Sun]Research Center of Chemical Fertilizer Catalyst,Fuzhou University,Fuzhou 350002,China

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Source :

中国化学工程学报(英文版)

ISSN: 1004-9541

CN: 11-3270/TQ

Year: 2022

Issue: 5

Volume: 45

Page: 41-50

3 . 8

JCR@2022

3 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count: -1

Chinese Cited Count:

30 Days PV: 1

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