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The selective hydrogenation of nitrile butadiene rubber (NBR) is an important process for the preparation of high value-added, high-performance hydrogenated NBR (HNBR). The C==C double bonds in the chain segment are hydrogenated while the nitrile group is unaffected, which can not only maintain its original oil resistance and wear resistance, but also greatly improve its weather resistance and ozone resistance. This article introduces several processes of NBR hydrogenation and emphatically reviewed the research progress and development direction of NBR heterogeneous catalytic hydrogenation. The effects of pore structure, surface properties and the active components of the supported catalyst on the hydrogenation performance of NBR is discussed. Additionally, the solvent effect, and the recovery and regeneration of catalyst in the heterogeneous hydrogenation process are summarized. It is proposed that solvent has an important influence on the catalytic hydrogenation rate and hydrogenation degree, and the hydrogen bond acceptance ability (β value) of solvent is the key factor affecting the hydrogenation performance. The main cause of catalyst deactivation is the coverage of the surface active sites by polymer, and washing with the effective solvent or modification of catalyst surface can expose the active sites again, thereby restoring the hydrogenation activity. Finally, the future research directions of heterogeneous catalytic hydrogenation for high value-added HNBR, including catalyst design, solvent effect and catalyst regeneration, are prospected. © 2022 Chemical Industry Press. All rights reserved.
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Chemical Industry and Engineering Progress
ISSN: 1000-6613
CN: 11-1954/TQ
Year: 2022
Issue: 9
Volume: 41
Page: 4790-4800
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WoS CC Cited Count: 0
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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