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author:

Zhou, Y. (Zhou, Y..) [1] | Wu, S. (Wu, S..) [2] | Huang, G. (Huang, G..) [3] | Zeng, J. (Zeng, J..) [4] | Meteku, B.E. (Meteku, B.E..) [5] | Tan, X. (Tan, X..) [6] | Lu, H. (Lu, H..) [7] | Li, F. (Li, F..) [8] | Cai, Z. (Cai, Z..) [9] | Wang, X. (Wang, X..) [10] | Zhang, M. (Zhang, M..) [11]

Indexed by:

Scopus

Abstract:

Intrinsic and surface defects are the crucial factors that affect the stability and luminescence efficiency of nanocrystals (NCs). Ion-doping and surface passivation are considered as the most effective strategies to suppress the intrinsic and surface defects of NCs, respectively. Herein, an efficient and facile double passivation process, simultaneously realizes ion-doping and surface passivation, for Cs3Cu2X5 (X[dbnd]Cl, Br and I) NCs is developed by using potassium oleate (K-OA) as passivator. K ion is used as ion-doping passivation and OA ion is used as the organic ligand for surface passivation of NCs. Compared to the free passivated NCs, the Photoluminescence quantum yield (PLQYs) of dual-passivated Cs3Cu2X5 (X[dbnd]Cl, Br and I) NCs increase significantly from 2.87%, 11.6% and 49.4–31%, 69.9%, and 97.2%, respectively. Moreover, the stability of proposed NCs is greatly improved (Cs3Cu2Cl5 NCs maintain 63% of PL efficiency after 100 h, Cs3Cu2Br5 and Cs3Cu2I5 NCs maintain 65% and 97% of PL efficiency after 100 days, respectively) at 50–86% relative humidity and room temperature under ambient atmosphere. © 2022 Elsevier B.V.

Keyword:

Copper(I)-based halide NCs Double passivation process Luminescence efficiency Stability

Community:

  • [ 1 ] [Zhou, Y.]College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, 363000, China
  • [ 2 ] [Wu, S.]College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, 363000, China
  • [ 3 ] [Huang, G.]Institute of Food Safety and Environment Monitoring, Fuzhou University, Fuzhou, 350108, China
  • [ 4 ] [Zeng, J.]College of Science, China University of Petroleum (East China), Qingdao, 266580, China
  • [ 5 ] [Meteku, B.E.]State Key Laboratory of Heavy Oil Processing, Center for Bioengineering and Biotechnology, China University of Petroleum (East China), Qingdao, 266580, China
  • [ 6 ] [Tan, X.]College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, 363000, China
  • [ 7 ] [Lu, H.]College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, 363000, China
  • [ 8 ] [Li, F.]College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, 363000, China
  • [ 9 ] [Li, F.]Fujian Province Key Laboratory of Modern Analytical Science and Separation Technology, Minnan Normal University, Zhangzhou, 363000, China
  • [ 10 ] [Cai, Z.]College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, 363000, China
  • [ 11 ] [Cai, Z.]Fujian Province Key Laboratory of Modern Analytical Science and Separation Technology, Minnan Normal University, Zhangzhou, 363000, China
  • [ 12 ] [Wang, X.]Human Phenome Institute, Fudan University, Shanghai, 200433, China
  • [ 13 ] [Zhang, M.]College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, 363000, China
  • [ 14 ] [Zhang, M.]Fujian Province Key Laboratory of Modern Analytical Science and Separation Technology, Minnan Normal University, Zhangzhou, 363000, China

Reprint 's Address:

  • [Zhang, M.]College of Chemistry, China

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Source :

Journal of Alloys and Compounds

ISSN: 0925-8388

Year: 2022

Volume: 918

6 . 2

JCR@2022

5 . 8 0 0

JCR@2023

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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