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author:

Zhang, Lei (Zhang, Lei.) [1] | Hu, Oudong (Hu, Oudong.) [2] | Zhang, Jin (Zhang, Jin.) [3] | Hou, Linxi (Hou, Linxi.) [4] | Ye, Dezhan (Ye, Dezhan.) [5] | Jiang, Xiancai (Jiang, Xiancai.) [6] | Xiao, Gao (Xiao, Gao.) [7]

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EI

Abstract:

Integrating high ionic conductivity and robust mechanical properties into one hydrogel remains challenging to date. In this paper, poly(vinyl alcohol)/carboxymethyl chitosan/tannic acid/NaCl/glycerol (PCTNG) organohydrogel was prepared by introducing tannic acid (TA), NaCl and glycerol (Gly) into poly(vinyl alcohol)/carboxymethyl chitosan (PVA/CMCS) simultaneously. Owing to the multiple hydrogen bonding complexations, the salting-out effect and metal coordination, the PCTNG organohydrogel showed an attractive overall performance with high tensile strength (2.02 MPa), large elongation at break (570.82%), superb ionic conductivity (3.05 S/m), excellent thermoplasticity and thermally assisted self-healing ability. Moreover, the introduction of Gly made PCTNG organohydrogel had high anti-freezing and anti-dehydration properties. The introduction of TA and NaCl endowed PCTNG organohydrogel with anti-bacterial properties. A flexible strain sensor was made based on this organoydrogel and this strain sensor could detect various human activities. This study provided a simple and promising strategy for manufacturing ionic conductive organohydrogel for flexible wearable devices. Graphical abstract: [Figure not available: see fulltext.] © 2022, The Author(s), under exclusive licence to Springer Nature B.V.

Keyword:

Chitosan Dehydration Hydrogen bonds Ionic conductivity Ionic strength Polyvinyl alcohols Sodium chloride Strain Tensile strength Wearable sensors

Community:

  • [ 1 ] [Zhang, Lei]School of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Hu, Oudong]School of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Zhang, Jin]School of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 4 ] [Hou, Linxi]School of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 5 ] [Ye, Dezhan]State Key Laboratory of New Textile Materials and Advanced Processing Technologies, Wuhan Textile University, No. 1 Yangguang Avenue, Jiangxia District, Hubei, Wuhan; 430200, China
  • [ 6 ] [Jiang, Xiancai]School of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 7 ] [Jiang, Xiancai]Qingyuan Innovation Laboratory, Quanzhou; 362114, China
  • [ 8 ] [Xiao, Gao]College of Environment and Safety Engineering, Fuzhou University, Fuzhou; 350108, China

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Source :

Cellulose

ISSN: 0969-0239

Year: 2022

Issue: 17

Volume: 29

Page: 9323-9339

5 . 7

JCR@2022

4 . 9 0 0

JCR@2023

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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