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author:

Wang, Yingshu (Wang, Yingshu.) [1] (Scholars:王莹淑) | Yang, Juan (Yang, Juan.) [2] | Liu, Siyu (Liu, Siyu.) [3] | Che, Xiaogang (Che, Xiaogang.) [4] | He, Songjie (He, Songjie.) [5] | Liu, Zhibin (Liu, Zhibin.) [6] | Wang, Man (Wang, Man.) [7] | Wang, Xiaoting (Wang, Xiaoting.) [8] | Qiu, Jieshan (Qiu, Jieshan.) [9]

Indexed by:

EI Scopus SCIE

Abstract:

Zinc-ion hybrid capacitors (ZIHC) demonstrate impressive charge-storage performance and intrinsic safety due to the inherited superiorities of aqueous rechargeable batteries and supercapacitors. However, the promotion of electrochemical performance is usually hindered by the cathode materials that fail to hold high energy density and rate capability of ZIHC. The optimization of porous carbon cathodes into a hierarchical structure is an efficient strategy to break the bottlenecks of ZIHC. Herein, a metal oxide space-confined strategy is proposed to build 3D graphene-like porous carbon nanosheets (3DPC) with doping of O and S heteroatoms by using low-cost aromatic hydrocarbons as precursors. It is found that the obtained 3DPC consists of micro-, mseo- and macropores and further delivers a high specific surface area of 2813 m2 g-1 with a total pore volume of 1.82 cm3 g- 1. Specifically, such a well-defined hierarchical porosity of 3DPC coupled with rich O and S heteroatoms enables sufficient multilevel ion transport channels and large accessible surface sites to capture the Zn2+ ions. As a proof of concept demonstration, the assembled aqueous ZIHC by employing the 3DPC cathode exhibits a desirable capacity of 194 mAh g-1 at 0.5 A g-1 with a superior rate capability of 53% at 30 A g-1 and excellent cycling stability of over 88% after 15000 cycles. Moreover, the remarkable electrochemical performance of the 3DPC cathode can be well-preserved in the case of a quasi-solid-state ZIHC device under various harsh bent states, highlighting the promising application in flexible and wearable energy storage.

Keyword:

Aromatic hydrocarbons Hierarchical carbon nanosheets Multilevel ion channels One-step pyrolysis Zn-ion hybrid capacitors

Community:

  • [ 1 ] [Wang, Yingshu]Fuzhou Univ, Coll Chem Engn, Fuzhou 350002, Peoples R China
  • [ 2 ] [Yang, Juan]Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Peoples R China
  • [ 3 ] [Liu, Siyu]Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Peoples R China
  • [ 4 ] [Che, Xiaogang]Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Peoples R China
  • [ 5 ] [He, Songjie]Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Peoples R China
  • [ 6 ] [Wang, Man]Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Peoples R China
  • [ 7 ] [Wang, Xiaoting]Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Peoples R China
  • [ 8 ] [Liu, Zhibin]Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Liaoning Key Lab Energy Mat & Chem Engn, Dalian 116024, Peoples R China
  • [ 9 ] [Qiu, Jieshan]Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Liaoning Key Lab Energy Mat & Chem Engn, Dalian 116024, Peoples R China
  • [ 10 ] [Liu, Zhibin]Inst Zhejiang Univ Quzhou, Quzhou 324000, Peoples R China
  • [ 11 ] [Qiu, Jieshan]Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China

Reprint 's Address:

  • [Yang, Juan]Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Peoples R China;;[Liu, Zhibin]Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Liaoning Key Lab Energy Mat & Chem Engn, Dalian 116024, Peoples R China;;

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Source :

CARBON

ISSN: 0008-6223

Year: 2023

Volume: 201

Page: 624-632

1 0 . 5

JCR@2023

1 0 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:39

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 49

SCOPUS Cited Count: 53

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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