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author:

Wang, Xuan (Wang, Xuan.) [1] | Dong, Xiping (Dong, Xiping.) [2] | Feng, Xiaochen (Feng, Xiaochen.) [3] | Shi, Qinhao (Shi, Qinhao.) [4] | Wang, Jing (Wang, Jing.) [5] | Yin, Xuemin (Yin, Xuemin.) [6] | Zhang, Jiujun (Zhang, Jiujun.) [7] (Scholars:张久俊) | Zhao, Yufeng (Zhao, Yufeng.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

P2-phase layered cathode materials with distinguished electrochemical performance for sodium-ion batteries have attracted extensive attention, but they face critical challenges of transition metal layer sliding and unfavorable formation of hydration phase upon cycling, thus showing inferior long cycle life. Herein, a new approach is reported to modulate the local structure of P2 material by constructing a state-of-the-art in-plane BO3 triangle configuration ((Na0.67Ni0.3Co0.1Mn0.6O1.94(BO3)(0.02)). Both are unveiled experimentally and theoretically that such a structure can serve as a robust pillar to hold up the entire structure, by inhibiting the H2O insertion upon Na (de)intercalation and preventing the structure from deformation, which significantly boost the long cycle capability of P2-materials. Meanwhile, more Na ions in the architecture are enabled to site on the edge sharing octahedrons (Na-e), thus benefiting the Na+ transportation. Consequently, the as produced material demonstrates an ultralow volume variation (1.8%), and an outstanding capacity retention of 80.1% after 1000 cycles at 2 C. This work sheds light on efficient architecture modulation of layered oxides through proper nonmetallic element doping.

Keyword:

BO3 configuration cathode materials P2 phase sodium-ion batteries suppress sliding

Community:

  • [ 1 ] [Wang, Xuan]Shanghai Univ, Inst Sustainable Energy, Shanghai 200444, Peoples R China
  • [ 2 ] [Dong, Xiping]Shanghai Univ, Inst Sustainable Energy, Shanghai 200444, Peoples R China
  • [ 3 ] [Feng, Xiaochen]Shanghai Univ, Inst Sustainable Energy, Shanghai 200444, Peoples R China
  • [ 4 ] [Shi, Qinhao]Shanghai Univ, Inst Sustainable Energy, Shanghai 200444, Peoples R China
  • [ 5 ] [Yin, Xuemin]Shanghai Univ, Inst Sustainable Energy, Shanghai 200444, Peoples R China
  • [ 6 ] [Zhang, Jiujun]Shanghai Univ, Inst Sustainable Energy, Shanghai 200444, Peoples R China
  • [ 7 ] [Zhao, Yufeng]Shanghai Univ, Inst Sustainable Energy, Shanghai 200444, Peoples R China
  • [ 8 ] [Wang, Xuan]Shanghai Univ, Coll Sci, Shanghai 200444, Peoples R China
  • [ 9 ] [Dong, Xiping]Shanghai Univ, Coll Sci, Shanghai 200444, Peoples R China
  • [ 10 ] [Feng, Xiaochen]Shanghai Univ, Coll Sci, Shanghai 200444, Peoples R China
  • [ 11 ] [Shi, Qinhao]Shanghai Univ, Coll Sci, Shanghai 200444, Peoples R China
  • [ 12 ] [Yin, Xuemin]Shanghai Univ, Coll Sci, Shanghai 200444, Peoples R China
  • [ 13 ] [Zhang, Jiujun]Shanghai Univ, Coll Sci, Shanghai 200444, Peoples R China
  • [ 14 ] [Zhao, Yufeng]Shanghai Univ, Coll Sci, Shanghai 200444, Peoples R China
  • [ 15 ] [Wang, Xuan]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 16 ] [Wang, Jing]Yanshan Univ, Key Lab Appl Chem Hebei Prov, Qinhuangdao 066004, Peoples R China
  • [ 17 ] [Zhang, Jiujun]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • [Zhang, Jiujun]Shanghai Univ, Inst Sustainable Energy, Shanghai 200444, Peoples R China;;[Zhao, Yufeng]Shanghai Univ, Inst Sustainable Energy, Shanghai 200444, Peoples R China;;[Zhang, Jiujun]Shanghai Univ, Coll Sci, Shanghai 200444, Peoples R China;;[Zhao, Yufeng]Shanghai Univ, Coll Sci, Shanghai 200444, Peoples R China;;[Wang, Jing]Yanshan Univ, Key Lab Appl Chem Hebei Prov, Qinhuangdao 066004, Peoples R China;;

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Source :

SMALL METHODS

ISSN: 2366-9608

Year: 2022

Issue: 1

Volume: 7

1 2 . 4

JCR@2022

1 0 . 7 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 20

SCOPUS Cited Count: 22

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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