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author:

Li, Nan (Li, Nan.) [1] | Shi, Zhaojiang (Shi, Zhaojiang.) [2] | Yuan, Yaofeng (Yuan, Yaofeng.) [3] | Li, Zhen (Li, Zhen.) [4] | Ye, Ke-Yin (Ye, Ke-Yin.) [5]

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EI

Abstract:

The preparation of biologically relevant spirodienones from arenol derivatives is typically performed in batch using superstoichiometric oxidants. Herein, we have developed an electrochemical dearomative spirocyclization in flow, featuring the use of electrons as the clean oxidant in a minimum amount of electrolytes or even the absence of electrolytes to afford diverse spirodienones in a short reaction time. © 2022 The Royal Society of Chemistry.

Keyword:

Electrolytes Oxidants

Community:

  • [ 1 ] [Li, Nan]Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Shi, Zhaojiang]Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Yuan, Yaofeng]Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 4 ] [Li, Zhen]Institute of Molecular Aggregation Science, Tianjin University, Tianjin; 300072, China
  • [ 5 ] [Ye, Ke-Yin]Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou; 350108, China

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Source :

Organic Chemistry Frontiers

ISSN: 2052-4110

Year: 2022

Issue: 23

Volume: 9

Page: 6586-6591

5 . 4

JCR@2022

4 . 6 0 0

JCR@2023

ESI HC Threshold:74

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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