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author:

Xu, Shen (Xu, Shen.) [1] | Huang, Jianying (Huang, Jianying.) [2] (Scholars:黄剑莹) | Li, Zengxing (Li, Zengxing.) [3] | Lei, Yonggang (Lei, Yonggang.) [4] | Zhang, Yingzhen (Zhang, Yingzhen.) [5] | Ng, Kim Hoong (Ng, Kim Hoong.) [6] | Lai, Yuekun (Lai, Yuekun.) [7] (Scholars:赖跃坤)

Indexed by:

EI Scopus SCIE

Abstract:

It is very attractive to find a cheap and efficient cocatalyst for enhancing the H-2 generation of graphitic carbon nitride (CN) under visible light. To achieve that, we proposed a novel two-step method to deposit sub-10 nm metallic Ni2P particles on the surface of CN sheets for a maximized interfacial contact. Characteristic results confirmed the establishment of ohmic heterojunction upon Ni2P-modification of CN, which deemed to be an effective measure to alleviate photo-charges recombination. In addition to facilitating spatial separation of charges, Ni2P could also enhance the optical properties of CN while reducing its impedance for interfacial electron shuttling. Better still, the P-end of Ni2P is highly electronegative, offering desirable H+-capturing capability for enhanced H-2 generation. These give rise to an improved H-2 production of Ni2P/CN composite, optimally at 645.3 mu mol g(-1)center dot h(-1) as compared to immeasurable H-2 yielded by the pristine CN. Such photocatalytic performance is even comparable to the Pt-modified CN photocatalyst (640.6 mu mol g(-1)center dot h(-1)). In recyclability test, a notable activity suppression of 33.17% was recorded after four reaction cycles. This can be ascribed to the pronounced photo-corrosion of the Ni2P cocatalyst during photoreaction. Nonetheless, a remarkably high H-2 generation (1328.6 mu mol g(-1) in 3 h) was still attained at 4(th) cycle. This justifies the effectiveness of our synthesized Ni2P cocatalyst in enhancing H-2 generation of CN under visible light irradiation.

Keyword:

g-C3N4 H-2 production Ni2P nanoparticle Ohmic contact Photocatalysis

Community:

  • [ 1 ] [Xu, Shen]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC CF, Fuzhou 350116, Peoples R China
  • [ 2 ] [Huang, Jianying]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC CF, Fuzhou 350116, Peoples R China
  • [ 3 ] [Li, Zengxing]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC CF, Fuzhou 350116, Peoples R China
  • [ 4 ] [Lei, Yonggang]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC CF, Fuzhou 350116, Peoples R China
  • [ 5 ] [Zhang, Yingzhen]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC CF, Fuzhou 350116, Peoples R China
  • [ 6 ] [Ng, Kim Hoong]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC CF, Fuzhou 350116, Peoples R China
  • [ 7 ] [Lai, Yuekun]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC CF, Fuzhou 350116, Peoples R China
  • [ 8 ] [Huang, Jianying]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 9 ] [Lai, Yuekun]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 10 ] [Ng, Kim Hoong]Ming Chi Univ Technol, Dept Chem Engn, New Taipei City 24301, Taiwan

Reprint 's Address:

  • [Ng, Kim Hoong]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC CF, Fuzhou 350116, Peoples R China;;[Lai, Yuekun]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC CF, Fuzhou 350116, Peoples R China;;

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Source :

JOURNAL OF CLEANER PRODUCTION

ISSN: 0959-6526

Year: 2023

Volume: 402

9 . 8

JCR@2023

9 . 8 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:35

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 23

SCOPUS Cited Count: 20

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Online/Total:275/10041950
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