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author:

Liu, Jingjing (Liu, Jingjing.) [1] | Zhan, Yuanjin (Zhan, Yuanjin.) [2] | Qiu, Bin (Qiu, Bin.) [3] (Scholars:邱彬) | Lin, Zhenyu (Lin, Zhenyu.) [4] (Scholars:林振宇) | Guo, Longhua (Guo, Longhua.) [5]

Indexed by:

EI Scopus SCIE

Abstract:

The development of an instrument-free, on-site, real-time, sensitive, and visualized fluoride-ion (F-) content rapid detection strategy is crucial to ensuring the health of the population. Smart microdevices that are portable, directly read, and easy to operate have recently attracted much attention. Herein, a ratiometric fluorescent probe (AA-CDs@[Ru(bpy)3]2+)-based smartphone sens-ing platform was developed for the detection of F-. The red fluorescent ruthenium bipyridine [Ru(bpy)3]2+ molecule was chosen as the reference signal, and the carbon dots (AA-CDs) with Al3+ aggregation-induced enhanced emission (AIE) were designed as the response signal. The ratiometric probe fluorescence changed continuously from red to cyan in response to different concentrations of F-, and the red-green-blue (RGB) channel values of the fluorescence image were extracted through the smartphone color recognition application (APP). There was a linear relationship between the blue-red (B/R) ratio and the F- concentration, with a limit of detection (LOD) of 1.53 mu M, far below the allowable content of F- in drinking water prescribed by the World Health Organization. The F- content was rapidly detected on-site with satisfactory repeatability and relative standard deviation using several water and toothpaste samples as the real sample. The platform features low cost, portability, easy operation, and good stability, selectivity, and repeatability, which provides a powerful tool for the visual quantitative detection of smartphone-based microsensing platforms possibly in the fields of environmental protection, diagnosis, and food safety assessment.

Keyword:

AIE carbon dot F- ratiometric fluorescence RGB smartphone

Community:

  • [ 1 ] [Liu, Jingjing]Fujian Polytech Normal Univ, Fujian Univ & Coll Engn Res Ctr Soft Plast Packagi, Fuqing 350300, Fujian, Peoples R China
  • [ 2 ] [Qiu, Bin]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fuzhou 350116, Peoples R China
  • [ 3 ] [Lin, Zhenyu]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fuzhou 350116, Peoples R China
  • [ 4 ] [Guo, Longhua]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fuzhou 350116, Peoples R China
  • [ 5 ] [Zhan, Yuanjin]Fudan Univ, Dept Chem, State Key Lab Mol Engn Polymers & Chem, Shanghai 200433, Peoples R China
  • [ 6 ] [Guo, Longhua]Jiaxing Univ, Coll Biol, Jiaxing Key Lab Mol Recognit & Sensing, Chem Sci & Engn, Jiaxing 314001, Peoples R China

Reprint 's Address:

  • [Guo, Longhua]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fuzhou 350116, Peoples R China;;[Zhan, Yuanjin]Fudan Univ, Dept Chem, State Key Lab Mol Engn Polymers & Chem, Shanghai 200433, Peoples R China;;[Guo, Longhua]Jiaxing Univ, Coll Biol, Jiaxing Key Lab Mol Recognit & Sensing, Chem Sci & Engn, Jiaxing 314001, Peoples R China;;

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Source :

ACS SENSORS

ISSN: 2379-3694

Year: 2023

8 . 3

JCR@2023

8 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:39

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 48

SCOPUS Cited Count: 48

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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