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author:

Xiang, Jingjing (Xiang, Jingjing.) [1] | Hao, Youchen (Hao, Youchen.) [2] | Gao, Yuting (Gao, Yuting.) [3] | Ji, Lei (Ji, Lei.) [4] | Wang, Li (Wang, Li.) [5] | Sun, Guoxing (Sun, Guoxing.) [6] | Tang, Yuxin (Tang, Yuxin.) [7] (Scholars:汤育欣) | Zhu, Yaofeng (Zhu, Yaofeng.) [8] | Jiang, Yinzhu (Jiang, Yinzhu.) [9]

Indexed by:

EI Scopus SCIE

Abstract:

Iron hexacyanoferrate (FeHCF) is regarded as a promising cathode material of sodium-ion batteries (SIBs) due to the merits of easy preparation, low cost and three-dimensional open framework. However, the practical application of FeHCF is highly restricted by the intrinsic [Fe(CN)6]4-vacancy and coordinated water as well as nanoscale particles. Herein, sodium citrate is introduced to mediate the drawbacks of FeHCF, resulting in microscale particles with less water content. Accordingly, the modified sample, FeHCF-3, achieved the performance of 92 mA h g-1 at 100 mA g-1 and 80 % capacity retention after 300 cycles. Furthermore, an optimal iron hexacyanoferrate (FeHCF-H-2) with high-salt-concentration preparation is designed and performs a good reversibility of 96 mA h g-1 after 700 cycles at 100 mA g-1. Such strategy may drive the application of high-tap, low-defect and stable cathode for SIBs.(c) 2023 Elsevier B.V. All rights reserved.

Keyword:

Good reversibility Iron hexacyanoferrate Low vacancy Sodium citrate Sodium-ion batteries

Community:

  • [ 1 ] [Xiang, Jingjing]Zhejiang Sci Tech Univ, Sch Mat Sci & Engn, Hangzhou 310018, Peoples R China
  • [ 2 ] [Zhu, Yaofeng]Zhejiang Sci Tech Univ, Sch Mat Sci & Engn, Hangzhou 310018, Peoples R China
  • [ 3 ] [Hao, Youchen]Zhejiang Univ, ZJU Hangzhou Global Sci & Technol Innovat Ctr, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China
  • [ 4 ] [Gao, Yuting]Zhejiang Univ, ZJU Hangzhou Global Sci & Technol Innovat Ctr, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China
  • [ 5 ] [Jiang, Yinzhu]Zhejiang Univ, ZJU Hangzhou Global Sci & Technol Innovat Ctr, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China
  • [ 6 ] [Ji, Lei]Baotou Res Inst Rare Earths, State Key Lab Baiyunobo Rare Earth Resource Res &, Baotou 014030, Peoples R China
  • [ 7 ] [Wang, Li]Baotou Res Inst Rare Earths, State Key Lab Baiyunobo Rare Earth Resource Res &, Baotou 014030, Peoples R China
  • [ 8 ] [Jiang, Yinzhu]Baotou Res Inst Rare Earths, State Key Lab Baiyunobo Rare Earth Resource Res &, Baotou 014030, Peoples R China
  • [ 9 ] [Sun, Guoxing]Univ Macau, Inst Appl Phys & Mat Engn, Joint Key Lab Minist Educ, Ave Univ, Taipa, Macau, Peoples R China
  • [ 10 ] [Tang, Yuxin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • [Zhu, Yaofeng]Zhejiang Sci Tech Univ, Sch Mat Sci & Engn, Hangzhou 310018, Peoples R China;;[Jiang, Yinzhu]Zhejiang Univ, ZJU Hangzhou Global Sci & Technol Innovat Ctr, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China;;

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2023

Volume: 946

5 . 8

JCR@2023

5 . 8 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:49

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 6

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Online/Total:233/10061964
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