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author:

Tong, M.-H. (Tong, M.-H..) [1] | Chen, Y.-X. (Chen, Y.-X..) [2] | Wang, T.-M. (Wang, T.-M..) [3] | Lin, S.-W. (Lin, S.-W..) [4] | Li, G. (Li, G..) [5] | Zhou, Q.-Q. (Zhou, Q.-Q..) [6] | Chen, R. (Chen, R..) [7] | Jiang, X. (Jiang, X..) [8] | Liao, H.-G. (Liao, H.-G..) [9] | Lu, C.-Z. (Lu, C.-Z..) [10]

Indexed by:

Scopus

Abstract:

Cerium element with a unique electric structure can be used to modify semiconductor photocatalysts to enhance their photocatalytic performances. In this work, Ce-doped TiO2 (Ce/TiO2) was successfully achieved using the sol-gel method. The structural characterization methods confirm that Ce was doped in the lattice of anatase TiO2, which led to a smaller grain size. The performance test results show that the Ce doped in anatase TiO2 significantly enhances the charge transport efficiency and broadens the light absorption range, resulting in higher photocatalytic performance. The Ce/TiO2 exhibited a photocurrent density of 10.9 μA/cm2 at 1.0 V vs. Ag/AgCl, 2.5 times higher than that of pure TiO2 (4.3 μA/cm2) under AM 1.5 G light. The hydrogen (H2) production rate of the Ce/TiO2 was approximately 0.33 μmol/h/g, which is more than twice as much as that of the pure anatase TiO2 (0.12 μmol/h/g). This work demonstrates the effect of Ce doping in the lattice of TiO2 for enhanced photocatalytic hydrogen production. © 2023 by the authors.

Keyword:

cerium-doped lattice structure photocatalytic photoelectrochemical water splitting TiO2 nanoparticles

Community:

  • [ 1 ] [Tong, M.-H.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Tong, M.-H.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 3 ] [Tong, M.-H.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 4 ] [Chen, Y.-X.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Chen, Y.-X.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 6 ] [Chen, Y.-X.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 7 ] [Chen, Y.-X.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 8 ] [Wang, T.-M.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 9 ] [Wang, T.-M.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 10 ] [Lin, S.-W.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 11 ] [Lin, S.-W.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 12 ] [Li, G.]State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China
  • [ 13 ] [Zhou, Q.-Q.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 14 ] [Zhou, Q.-Q.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 15 ] [Chen, R.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 16 ] [Chen, R.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 17 ] [Jiang, X.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 18 ] [Jiang, X.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 19 ] [Liao, H.-G.]State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China
  • [ 20 ] [Lu, C.-Z.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 21 ] [Lu, C.-Z.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 22 ] [Lu, C.-Z.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China

Reprint 's Address:

  • [Chen, Y.-X.]College of Chemistry, China;;[Lu, C.-Z.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, China;;[Liao, H.-G.]State Key Laboratory of Physical Chemistry of Solid Surfaces, China

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Related Keywords:

Source :

Molecules

ISSN: 1420-3049

Year: 2023

Issue: 6

Volume: 28

4 . 2

JCR@2023

4 . 2 0 0

JCR@2023

ESI HC Threshold:39

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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