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author:

Tan, L. (Tan, L..) [1] | Li, Y. (Li, Y..) [2] | Lv, Q. (Lv, Q..) [3] | Gan, Y. (Gan, Y..) [4] | Fang, Y. (Fang, Y..) [5] | Tang, Y. (Tang, Y..) [6] | Wu, L. (Wu, L..) [7]

Indexed by:

Scopus

Abstract:

The conversion of CO2 to valuable chemicals by photocatalysis has attracted widespread interesting. Owing to the linear structure of CO2 molecule with strong C[dbnd]O bond, the surface reaction is considered as one of the main issues to restrict the conversion efficiency. Herein, soluble UiO-66 has been developed as co-catalyst to enhance the photocatalytic performance for CO2 reduction. The soluble UiO-66 has presented the performance ca. 1.5 higher than the insoluble version, yielding 30.6 µmol/h for CO2 to CO conversion by using 5.0 mg sample. This improvement can be attributed to the preserved framework by soluble UiO-66. Therefore, the chemisorption of CO2 molecules can be improved, boosting the reduction reaction for CO production. This research provides a new path for a rational design of metal-organic framework (MOF) for photoredox catalysis, meanwhile inspiring advanced application of MOF catalysis with the soluble manner. © 2022 Elsevier B.V.

Keyword:

CO2 reduction CO production Metal organic framework Photocatalysis Soluble UiO-66

Community:

  • [ 1 ] [Tan, L.]Institute of Molecular Catalysis and In Situ/Operando Studies, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Li, Y.]Institute of Molecular Catalysis and In Situ/Operando Studies, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 3 ] [Lv, Q.]Institute of Molecular Catalysis and In Situ/Operando Studies, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 4 ] [Gan, Y.]Institute of Molecular Catalysis and In Situ/Operando Studies, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 5 ] [Fang, Y.]Institute of Molecular Catalysis and In Situ/Operando Studies, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 6 ] [Tang, Y.]Institute of Molecular Catalysis and In Situ/Operando Studies, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 7 ] [Wu, L.]Institute of Molecular Catalysis and In Situ/Operando Studies, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 8 ] [Fang, Y.]Institute of Molecular Catalysis and In Situ/Operando Studies, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China

Reprint 's Address:

  • [Tan, L.]Institute of Molecular Catalysis and In Situ/Operando Studies, China

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Source :

Catalysis Today

ISSN: 0920-5861

Year: 2023

Volume: 410

Page: 282-288

5 . 2

JCR@2023

5 . 2 0 0

JCR@2023

ESI HC Threshold:39

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 22

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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