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Abstract:
An electrochemical bromination of thiophenes from ammonium bromide is developed both in batch and continuous-flow conditions. Substituted thiophenes possessing 2-hydrogens selectively afford a series of 2-bromothiophenes while 2-substituted benzothiophenes generate 3-bromobenzo[b]thiophenes. Based on the cyclic voltammetric studies and literature, a bromine cation involved mechanism was proposed. © 2022 Wiley-VCH GmbH.
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European Journal of Organic Chemistry
ISSN: 1434-193X
Year: 2023
Issue: 7
Volume: 26
2 . 5
JCR@2023
2 . 5 0 0
JCR@2023
ESI HC Threshold:39
JCR Journal Grade:2
CAS Journal Grade:3
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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