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author:

Wu, H.-L. (Wu, H.-L..) [1] | Qi, M.-Y. (Qi, M.-Y..) [2] | Tang, Z.-R. (Tang, Z.-R..) [3] | Xu, Y.-J. (Xu, Y.-J..) [4]

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Abstract:

Semiconductor quantum dots (QDs), as a newfashioned light-absorbing material with great promise in artificial photosystems, generally exhibit attractive photoactivity and selectivity in organic photoredox transformation thanks to their tunable redox potential, high-efficiency light harvesting capability, and high extinction coefficient in the visible region. Utilizing QDs as a versatile platform to convert organic compounds into value-added feedstocks provides an effective way to alleviate energy and chemical feedstock supply problems. In this review, we concisely summarize the basic principles of photocatalytic organic conversions over semiconductor QDs and the effects of grain size, surface active sites and ligands on their catalytic performance. Then, we highlight the recent progress of QDs enabling multifarious photocatalytic organic transformations, including nitroaromatic reduction, selective alcohol oxidation, sulfide oxidation, C-H functionalization and so on. In the end, we discuss the current challenges and future prospects in further developing efficient semiconductor QD-based photocatalysts toward photoredox-catalyzed organic conversion. © 2023 The Royal Society of Chemistry.

Keyword:

Community:

  • [ 1 ] [Wu, H.-L.]College of Chemistry, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Qi, M.-Y.]College of Chemistry, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 3 ] [Tang, Z.-R.]College of Chemistry, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Xu, Y.-J.]College of Chemistry, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • [Tang, Z.-R.]College of Chemistry, China;;[Xu, Y.-J.]College of Chemistry, China

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Source :

Journal of Materials Chemistry A

ISSN: 2050-7488

Year: 2023

Issue: 7

Volume: 11

Page: 3262-3280

1 0 . 8

JCR@2023

1 0 . 8 0 0

JCR@2023

ESI HC Threshold:49

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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