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author:

Hong, Zhaoan (Hong, Zhaoan.) [1] | Hong, Wengting (Hong, Wengting.) [2] | Wang, Bicheng (Wang, Bicheng.) [3] | Cai, Qian (Cai, Qian.) [4] | He, Xu (He, Xu.) [5] | Liu, Wei (Liu, Wei.) [6]

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EI

Abstract:

1T-phase molybdenum disulfide (1T MoS2) can efficiently facilitate the charge transfer and provide the active site, exhibiting a better hydrogen evolution reaction (HER) than 2H MoS2. However, its thermodynamic instability becomes a major drawback that hinders its practical application. We report a chemical vapor deposition (CVD) method to grow MoS2 nanosheets with high 1T content (61.5%) by introducing an appropriate amount of antimony oxide. The 1T-2H hybrid structures grown in this mode are thermodynamically stable. 1T phase of the MoS2 produces a unique charge distribution that makes the S atoms at the 1T-2H interface more favorable for H adsorption, thus enhancing the HER activity on the MoS2 basal plane. This study has provided a new idea for the 1T-phase MoS2 preparation for efficient HER. © 2023 Elsevier B.V.

Keyword:

Antimony compounds Charge transfer Chemical vapor deposition Electrocatalysis Hydrogen Layered semiconductors Molybdenum disulfide Phase transitions

Community:

  • [ 1 ] [Hong, Zhaoan]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 2 ] [Hong, Zhaoan]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Hong, Wengting]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 4 ] [Wang, Bicheng]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 5 ] [Wang, Bicheng]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 6 ] [Cai, Qian]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 7 ] [He, Xu]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 8 ] [Liu, Wei]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 9 ] [Liu, Wei]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou; 350108, China

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Source :

Chemical Engineering Journal

ISSN: 1385-8947

Year: 2023

Volume: 460

1 3 . 4

JCR@2023

1 3 . 4 0 0

JCR@2023

ESI HC Threshold:35

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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