Proton-Conductive Polyoxometalate Architectures Constructed from Lanthanide-Incorporated Polyoxoniobate Cages - Details

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Abstract：

Two　new　extended　polyoxometalate　(POM)　architectures　based　on　lanthanide-incorporated　polyoxoniobate　(Ln-incorporated　PONb)　cages,　namely,　H4[CuII(en)2]4{K4(H2O)2[CuII(en)2]5[CuII5(trz)2(en)4(OH)2][Dy2CuII2(en)2(CO3)3(H2O)2(OH)3][Dy(H2O)4][DyNb23O68(H2O)4]2}·60H2O　(1,　en　=　ethylenediamine)　and　H20[CuII(en)2]4{[CuII(en)2]4[Dy2(C2O4)(H2O)4]2[(Nb32(OH)4(H2O)3O89]2}·54H2O　(2),　have　been　successfully　synthesized　and　structurally　characterized,　demonstrating　a　feasible　strategy　to　develop　functional　POM　materials.　In　addition,　the　proton　conductivity　and　magnetic　behaviors　of　both　1　and　2　were　studied.　©　2022　American　Chemical　Society.　All　rights　reserved.

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Oxides Rare earth elements

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[ 1 ] [Lai, Rong-Da]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fujian, Fuzhou; 350108, China
[ 2 ] [Zhu, Zeng-Kui]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fujian, Fuzhou; 350108, China
[ 3 ] [Wu, Yan-Lan]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fujian, Fuzhou; 350108, China
[ 4 ] [Sun, Yan-Qiong]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fujian, Fuzhou; 350108, China
[ 5 ] [Sun, Cai]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fujian, Fuzhou; 350108, China
[ 6 ] [Li, Xin-Xiong]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fujian, Fuzhou; 350108, China
[ 7 ] [Li, Xin-Xiong]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350108, China
[ 8 ] [Zheng, Shou-Tian]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fujian, Fuzhou; 350108, China

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Inorganic Chemistry

ISSN： 0020-1669

Year： 2022

Issue： 51

Volume： 61

Page： 21047-21054

4 . 6

JCR@2022

4 . 3 0 0

JCR@2023

ESI HC Threshold：74

JCR Journal Grade：1

CAS Journal Grade：1

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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