Stereoselective electrochemical carboxylation of α,β-unsaturated sulfones - Details

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Abstract：

As　an　attractive　C1　synthon,　carbon　dioxide　(CO2)　has　been　extensively　used　in　organic　synthesis　to　produce　carboxylic　acids.　In　this　research,　stereoselective　electrochemical　carboxylation　of　α,β-unsaturated　sulfones　has　been　developed　under　transition-metal-free　conditions.　All　the　cinnamic　acids　and　the　derivatives　are　obtained　selectively　in　the　E-configuration.　Besides,　arylpropiolates　also　can　be　produced　from　alkynyl　sulfones.　©　2023

Keyword：

Carbon dioxide Carboxylation Electrosynthesis α,β-Unsaturated carboxylic acid α,β-Unsaturated sulfone

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[ 1 ] [Yang Z.-X.]Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Lai L.]Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [Chen J.]Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 4 ] [Yan H.]Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Ye K.-Y.]Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 6 ] [Chen F.-E.]Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 7 ] [Chen F.-E.]Department of Chemistry, Engineering Center of Catalysis and Synthesis for Chiral Molecules, Fudan University, Shanghai, 200433, China
[ 8 ] [Chen F.-E.]Shanghai Engineering Research Center of Industrial Asymmetric Catalysis of Chiral Drugs, Fudan University, Shanghai, 200433, China

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Source ：

Chinese Chemical Letters

ISSN： 1001-8417

Year： 2023

Issue： 6

Volume： 34

9 . 4

JCR@2023

9 . 4 0 0

JCR@2023

ESI HC Threshold：39

JCR Journal Grade：1

CAS Journal Grade：2

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 11

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

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