Low-dimensional　inorganic-organic　hybrid　perovskiteswithhigh　moisture　tolerance　and　long-lived　charge　separation　states　havecaptured　significant　attention　in　the　field　of　optoelectronic　devices.To　further　achieve　the　relationship　between　crystal　structures　andstability,　as　well　as　charge　separation　behaviors,　three　one-dimensionalhybrid　perovskites　containing　electron-deficient　naphthalene　diimideammonium　(NDIEA)　and　electron-rich　iodoplumbate　chains,　[(H(2)NDIEA)Pb2I6]center　dot　2DMF　(1),　[(H(2)NDIEA)(2)Pb5I14　center　dot(DMF)(2)]center　dot　4DMF　(2),　and　[(HNDIEA)(2)Pb2I6]center　dot　3H(2)O　(3),　weresynthesized.　Crystal　structure　determinations　revealed　various　synthesisconditions　leading　to　different　stacking　modes,　especially　the　inorganiclead　iodide　fraction,　which　resulted　in　different　water　resistancesand　charge-separated　behaviors.　The　comprehensive　analysis　found　thatstrong　intermolecular　interactions　(anion-pi　interactionsand　pi-pi　interactions),　and　matching　energy　levelsbetween　protonated　NDIEA　and　iodoplumbate　chains,　can　facilitate　thegeneration　of　long-lived　charge　separation　states　and　extraordinarymoisture　stability,　even　in　the　water　environment.　In　addition,　theconductivity　behavior　of　3　was　also　explored　in　detail.　Low-dimensional　inorganic-organichybrid　perovskitescontaining　electron-deficient　naphthalene　diimide　ammoniums　and　electron-richiodoplumbate　chains　have　been　reported,　which　possess　long-lived　chargeseparation　states　and　extraordinary　moisture　stability.