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author:

Fang, Xiao (Fang, Xiao.) [1] | Chen, Lu (Chen, Lu.) [2] | Cheng, Hongrui (Cheng, Hongrui.) [3] | Bian, Xiaoqiong (Bian, Xiaoqiong.) [4] | Sun, Wenhao (Sun, Wenhao.) [5] | Ding, Kaining (Ding, Kaining.) [6] (Scholars:丁开宁) | Xia, Xinghe (Xia, Xinghe.) [7] | Chen, Xin (Chen, Xin.) [8] (Scholars:陈新) | Zhu, Jiefang (Zhu, Jiefang.) [9] | Zheng, Yuanhui (Zheng, Yuanhui.) [10] (Scholars:郑远辉)

Indexed by:

EI Scopus SCIE CSCD

Abstract:

Carbon nitride (CN) has attracted intensive attention as a visible light photocatalyst, but the rapid recombination of photogenerated charge carriers limits its photocatalytic activity. Herein, we develop a new strategy to construct both homojunction and ohmic junction into CN via selectively introducing metallized CN (MCN), which leads to rapid separation and transfer of photogenerated charge carriers. The polymerization of urea in the presence of KOH creates CN homojunction with amino and cyano groups. The subsequent molten salt treatment induces a new type of cyano-terminated CN that can be converted to MCN through photodoping, forming homojunction and ohmic contact coexisting CN (HOCN). The formed HOCN photocatalyst exhibits a high photocatalytic H-2 evolution rate of 18.5 mmol.g(-1).h(-1) under visible light irradiation, 45-fold higher than that of bulk CN. This strategy provides a new idea for designing ohmic contact between semiconductor and metal, and realizing efficient photocatalysis by improving charge separation and transfer.

Keyword:

carbon nitride homojunction hydrogen evolution ohmic contact photocatalysis

Community:

  • [ 1 ] [Fang, Xiao]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350116, Peoples R China
  • [ 2 ] [Chen, Lu]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350116, Peoples R China
  • [ 3 ] [Bian, Xiaoqiong]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350116, Peoples R China
  • [ 4 ] [Sun, Wenhao]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350116, Peoples R China
  • [ 5 ] [Ding, Kaining]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350116, Peoples R China
  • [ 6 ] [Xia, Xinghe]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350116, Peoples R China
  • [ 7 ] [Chen, Xin]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350116, Peoples R China
  • [ 8 ] [Zheng, Yuanhui]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350116, Peoples R China
  • [ 9 ] [Cheng, Hongrui]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China
  • [ 10 ] [Zheng, Yuanhui]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China
  • [ 11 ] [Zheng, Yuanhui]Fuzhou Univ, Coll Phys & Informat Engn, Fuzhou 350116, Peoples R China
  • [ 12 ] [Sun, Wenhao]Uppsala Univ, Dept Chem, Angstrom Lab, SE-75121 Uppsala, Sweden
  • [ 13 ] [Zhu, Jiefang]Uppsala Univ, Dept Chem, Angstrom Lab, SE-75121 Uppsala, Sweden
  • [ 14 ] [Zhu, Jiefang]East China Univ Sci & Technol, Key Lab Ultrafine Mat, Minist Educ, Shanghai 200237, Peoples R China

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Source :

NANO RESEARCH

ISSN: 1998-0124

Year: 2023

Issue: 7

Volume: 16

Page: 8782-8792

9 . 6

JCR@2023

9 . 6 0 0

JCR@2023

ESI Discipline: PHYSICS;

ESI HC Threshold:30

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 10

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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