Aqueous　zinc-ion　batteries　(AZIBs)　show　enormous　potential　as　a　large-scale　energy　storage　technique.　However,　the　growth　of　Zn　dendrites　and　serious　side　reactions　occurring　at　the　Zn　anode　hinder　the　practical　application　of　AZIBs.　For　the　first　time,　we　reported　a　fluorine-containing　surfactant,　i.e.,　potassium　perfluoro-1-butanesulfonate　(PPFBS),　as　an　additive　to　the　2　M　ZnSO4　electrolyte.　Benefitting　from　its　hydrophilic　sulfonate　anion　and　hydrophobic　long　fluorocarbon　chain,　PPFBS　can　promote　the　uniform　distribution　of　Zn2+　flux　at　the　anode/electrolyte　interface,　allowing　the　Zn/Zn　cell　to　cycle　for　2200　h.　Furthermore,　PPFBS　could　inhibit　side　reactions　due　to　the　existence　of　the　perfluorobutyl　sulfonate　(C4F9SO3-)　adsorption　layer　and　the　presence　of　C4F9SO3-　in　the　solvation　structure　of　Zn2+.　The　former　can　reduce　the　amount　of　H2O　molecules　and　SO42-　in　contact　with　the　Zn　anode　and　C4F9SO3-　entering　the　Zn2+-solvation　structure　by　replacing　SO42-.　The　Zn/Cu　cell　exhibits　a　superior　average　CE　of　99.47%　over　500　cycles.　When　coupled　with　the　V2O5　cathode,　the　full　cell　shows　impressive　cycle　stability.　This　work　provides　a　simple,　effective,　and　economical　solution　to　the　common　issues　of　the　Zn　anode.