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author:

Hu, X. (Hu, X..) [1] | Chen, S. (Chen, S..) [2] | Wang, H. (Wang, H..) [3] | Zhou, Z.-X. (Zhou, Z.-X..) [4] | Min, J. (Min, J..) [5] | Chen, Q. (Chen, Q..) [6] | Hong, M. (Hong, M..) [7] | Fu, H. (Fu, H..) [8]

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Abstract:

Hydrogels are important materials for mechanical sensors of artificial intelligence, and their good electrical conductivity and mechanical properties have broad application space in the field of multifunctional materials. However, it is still a challenge to prepare hydrogels with excellent conductivity and sensing, anti-freezing and water retention, resilience and fatigue resistance. Herein, chitosan/poly(acrylic acid-acrylamide‑sodium p-styrenesulfonate)/glycerol/samarium hydrate (C/P/G/S) double-network (DN) hydrogels were prepared by Interpenetrating Polymer Networks (IPNs) of chitosan (CS) with acrylic acid (AA), acrylamide (AM), sodium p-styrenesulfonate (SSS), glycerol (GL) and samarium hydrate (SH) under ultraviolet (UV) light. The C/P/G/S DN hydrogels have satisfactory mechanical properties, conductivity, mechanical strain sensing performances, water retention and frost resistance capacities. Specially, the compressive stress of hydrogels at 80% compressive strain is up to 1.7 MPa. It also shows preeminent fatigue resistance and resilience in continuous cyclic stretching and cyclic compression (5 and 100 times). The conductivity of the hydrogels can reach 1.9 S/m when the SH is 1.8 g. Meanwhile, mechanical strain sensing tests of the hydrogels at room temperature and low temperature were also performed simultaneously. The hydrogels have stable mechanical strain sensing properties and good electrical conductivity even at −20 °C. More importantly, when C/P/G/S DN hydrogels were placed at room temperature and ventilated for 30 days, the water loss rate of hydrogels was only 13.9%. © 2023 Elsevier B.V.

Keyword:

Anti-freezing Composite hydrogels Mechanical sensors Samarium hydrate

Community:

  • [ 1 ] [Hu X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 2 ] [Hu X.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 3 ] [Hu X.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 4 ] [Chen S.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 5 ] [Wang H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 6 ] [Wang H.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 7 ] [Wang H.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 8 ] [Zhou Z.-X.]School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, China
  • [ 9 ] [Min J.]School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, China
  • [ 10 ] [Chen Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 11 ] [Hong M.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 12 ] [Fu H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 13 ] [Fu H.]School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, China
  • [ 14 ] [Fu H.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China

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Source :

Reactive and Functional Polymers

ISSN: 1381-5148

Year: 2023

Volume: 190

4 . 5

JCR@2023

4 . 5 0 0

JCR@2023

ESI HC Threshold:39

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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