Synthesis and Characterization of Luminescent Binuclear μ-HS Cu(I) Complexes - Details

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Photoactive　Cu(I)　complexes　are　promising　luminescent　materials　owing　to　their　abundant　reserves　and　marvelous　biocompatibility.　In　this　work,　we　report　the　synthesis　and　characterization　of　two　binuclear　sulfur-bridged　Cu(I)　complexes　(POP)2Cu2(μ-HS/Cl)2　⋅　0.92MeOH　1　(POP=(oxybis(2,1-phenylene))bis(diphenylphosphine))　and　(POP)2Cu2(μ-HS)2　2,　which　were　prepared　by　one-pot　facile　solvothermal　method　with　copper-4-tert-butylbenzenethiol　(CuSC6H4tBu)　and　POP　as　precursors.　Complex　1　exhibits　sky-blue　emission　while　complex　2　displays　blue.　Complex　1　was　systemically　investigated　by　PXRD,　UV-vis　spectrum,　IR,　TGA　and　steady-state　spectra.　Temperature-dependent　steady-state　emission　and　decay　lifetime　indicate　that　complex　1　is　a　typical　phosphorescent　emitter.　©　2023　Wiley-VCH　GmbH.

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Biocompatibility Chelation Copper compounds Crystal growth Luminescence Synthesis (chemical)

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[ 1 ] [Li, Ting-Ting]College of Chemistry, Fuzhou University, Fuzhou; 350116, China
[ 2 ] [Li, Ting-Ting]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen; 361021, China
[ 3 ] [Li, Ting-Ting]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
[ 4 ] [Kuang, Xiaofei]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen; 361021, China
[ 5 ] [Kuang, Xiaofei]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
[ 6 ] [Kuang, Xiaofei]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou; 350108, China
[ 7 ] [Kuang, Xiaofei]University of Chinese Academy of Sciences, Beijing; 100049, China
[ 8 ] [Wang, Ming-Ming]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen; 361021, China
[ 9 ] [Wang, Ming-Ming]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
[ 10 ] [Yang, Hui]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen; 361021, China
[ 11 ] [Yang, Hui]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
[ 12 ] [Mi, Ying-Hao]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen; 361021, China
[ 13 ] [Mi, Ying-Hao]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
[ 14 ] [Mi, Ying-Hao]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou; 350108, China
[ 15 ] [Lu, Can-Zhong]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen; 361021, China
[ 16 ] [Lu, Can-Zhong]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
[ 17 ] [Lu, Can-Zhong]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou; 350108, China
[ 18 ] [Lu, Can-Zhong]University of Chinese Academy of Sciences, Beijing; 100049, China

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Source ：

Zeitschrift fur Anorganische und Allgemeine Chemie

ISSN： 0044-2313

Year： 2023

Issue： 11-12

Volume： 649

1 . 1

JCR@2023

1 . 1 0 0

JCR@2023

ESI HC Threshold：39

JCR Journal Grade：4

CAS Journal Grade：4

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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