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author:

Wang, Yubing (Wang, Yubing.) [1] | Wu, Xiaoxi (Wu, Xiaoxi.) [2] | Zhang, Jiarui (Zhang, Jiarui.) [3] | Xu, Zhicheng (Xu, Zhicheng.) [4] | Feng, Jiangtao (Feng, Jiangtao.) [5] | Li, Mingtao (Li, Mingtao.) [6] | Chen, Jie (Chen, Jie.) [7] (Scholars:陈杰) | Yan, Wei (Yan, Wei.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

New strategies are required to modify adsorbents that possess numerous accessible chelating sites with high utilization, in order to achieve both rapid uptake and high capacity for the contaminants, which are still urgently needed. This study introduces a novel integration of a conjugated microporous polymer (CMP) material with conventional polyaniline, representing the first instance of such a combination. By amalgamating the doping properties of polyaniline with the highly stable structure and extensive microporous attributes of CMP, we achieve a synergistic effect. The conjugated microporous polyaniline is subjected to a concentrated sulfuric acid modification (SD-CMPA), enabling simultaneous oxidation, doping, and pore channel modification in a single step. The resulting SD-CMPA exhibits a record-breaking maximum adsorption capacity for Hg2+, reaching as high as 1720 mg center dot g(-1), as well as a benchmark distribution coefficient of 2.5 x 10(8) mL center dot g(-1). Moreover, it demonstrates robust reusability, retaining over 96% of its adsorption capacity for at least six cycles. These remarkable features enable the achievement of ultra-deep-water purification to 0.452 ppb in an effective manner. The impressive performance of SD-CMPA can be attributed to the abundance of nitrogen-containing groups, particularly the tertiary amine nitrogen in the material skeleton, as supported by X-ray photoelectron spectroscopy and density functional theory calculations. The results presented in this study demonstrate the exceptional potential of SD-CMPA for high-performance environmental remediation.

Keyword:

Conjugated microporous polymers Large adsorption capacity Mercury ion adsorption Sulfate doping Ultra-deep-water purification

Community:

  • [ 1 ] [Wang, Yubing]Xi An Jiao Tong Univ, Dept Environm Sci & Engn, Xian Key Lab Solid Waste Recycling & Resource Reco, Xian 710049, Peoples R China
  • [ 2 ] [Wu, Xiaoxi]Xi An Jiao Tong Univ, Dept Environm Sci & Engn, Xian Key Lab Solid Waste Recycling & Resource Reco, Xian 710049, Peoples R China
  • [ 3 ] [Zhang, Jiarui]Xi An Jiao Tong Univ, Dept Environm Sci & Engn, Xian Key Lab Solid Waste Recycling & Resource Reco, Xian 710049, Peoples R China
  • [ 4 ] [Xu, Zhicheng]Xi An Jiao Tong Univ, Dept Environm Sci & Engn, Xian Key Lab Solid Waste Recycling & Resource Reco, Xian 710049, Peoples R China
  • [ 5 ] [Feng, Jiangtao]Xi An Jiao Tong Univ, Dept Environm Sci & Engn, Xian Key Lab Solid Waste Recycling & Resource Reco, Xian 710049, Peoples R China
  • [ 6 ] [Yan, Wei]Xi An Jiao Tong Univ, Dept Environm Sci & Engn, Xian Key Lab Solid Waste Recycling & Resource Reco, Xian 710049, Peoples R China
  • [ 7 ] [Wang, Yubing]Xi An Jiao Tong Univ, Sch Energy & Power Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R China
  • [ 8 ] [Wu, Xiaoxi]Xi An Jiao Tong Univ, Sch Energy & Power Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R China
  • [ 9 ] [Zhang, Jiarui]Xi An Jiao Tong Univ, Sch Energy & Power Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R China
  • [ 10 ] [Xu, Zhicheng]Xi An Jiao Tong Univ, Sch Energy & Power Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R China
  • [ 11 ] [Li, Mingtao]Xi An Jiao Tong Univ, Sch Energy & Power Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R China
  • [ 12 ] [Yan, Wei]Xi An Jiao Tong Univ, Sch Energy & Power Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R China
  • [ 13 ] [Chen, Jie]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Fujian, Peoples R China

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Source :

SEPARATION AND PURIFICATION TECHNOLOGY

ISSN: 1383-5866

Year: 2023

Volume: 324

8 . 2

JCR@2023

8 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:39

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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