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author:

Wang, Baisen (Wang, Baisen.) [1] | Yue, Zhongwei (Yue, Zhongwei.) [2] | Chen, Zhiyi (Chen, Zhiyi.) [3] | Zhang, Yanxiang (Zhang, Yanxiang.) [4] | Fang, Huihuang (Fang, Huihuang.) [5] (Scholars:方辉煌) | Ai, Na (Ai, Na.) [6] (Scholars:艾娜) | Wang, Ruijing (Wang, Ruijing.) [7] | Yang, Fan (Yang, Fan.) [8] | Guan, Chengzhi (Guan, Chengzhi.) [9] | Jiang, San Ping (Jiang, San Ping.) [10] | Shao, Zongping (Shao, Zongping.) [11] | Luo, Yu (Luo, Yu.) [12] | Chen, Kongfa (Chen, Kongfa.) [13] (Scholars:陈孔发)

Indexed by:

EI Scopus SCIE

Abstract:

Nanostructured anodes generate massive reaction sites to oxidize fuels in solid oxide fuel cells (SOFCs); however, the nonexistence of a practically viable approach for the construction of nanostructures and the retention of these nanostructures under the harsh operating conditions of SOFCs poses a significant challenge. Herein, a simple procedure is reported for the construction of a nanostructured Ni-Gd-doped CeO2 anode based on the direct assembly of pre-formed nanocomposite powder with strong metal-oxide interaction. The directly assembled anode forms heterointerfaces with the electrolyte owing to the electrochemical polarization current and exhibits excellent structural robustness against thermal ripening. An electrolyte-supported cell with the directly assembled anode produces a peak power density of 0.73 W cm(-2) at 800 & DEG;C, while maintaining stability for 100 h, which is in contrast to the drastic degradation of the cermet anode prepared using the conventional method. These findings provide clarity on the design and construction of durable nanostructured anodes and other electrodes for SOFCs.

Keyword:

cermet anodes direct assembly electrode-electrolyte interfaces metal-oxide interactions nanostructures

Community:

  • [ 1 ] [Wang, Baisen]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Yue, Zhongwei]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Chen, Zhiyi]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Chen, Kongfa]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Zhang, Yanxiang]Harbin Inst Technol, Sch Mat Sci & Engn, Natl Key Lab Precis Hot Proc Met, MIIT Key Lab Adv Struct Funct Integrated Mat & Gre, Harbin 150001, Peoples R China
  • [ 6 ] [Fang, Huihuang]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC CF, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Luo, Yu]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC CF, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Ai, Na]Fuzhou Univ, Fujian Coll Assoc Instrumental Anal Ctr, Fuzhou 350108, Fujian, Peoples R China
  • [ 9 ] [Wang, Ruijing]Shanghai Tech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
  • [ 10 ] [Yang, Fan]Shanghai Tech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
  • [ 11 ] [Guan, Chengzhi]Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China
  • [ 12 ] [Jiang, San Ping]Foshan Xianhu Lab Adv Energy Sci & Technol, Guangdong Lab, Foshan 528216, Peoples R China
  • [ 13 ] [Jiang, San Ping]Curtin Univ, WA Sch Mines Minerals Energy & Chem Engn, Perth, WA 6102, Australia
  • [ 14 ] [Shao, Zongping]Nanjing Tech Univ, Coll Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Peoples R China

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Source :

SMALL

ISSN: 1613-6810

Year: 2023

Issue: 46

Volume: 19

1 3 . 0

JCR@2023

1 3 . 0 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:49

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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