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author:

Niu, Yu (Niu, Yu.) [1] | Shen, Jinni (Shen, Jinni.) [2] (Scholars:沈锦妮) | Guo, Wenqin (Guo, Wenqin.) [3] | Zhu, Xiaoyan (Zhu, Xiaoyan.) [4] | Guo, Lanlan (Guo, Lanlan.) [5] | Wang, Yueqi (Wang, Yueqi.) [6] | Li, Fuying (Li, Fuying.) [7]

Indexed by:

Scopus SCIE

Abstract:

This study focuses on the development of heterojunction photocatalysts for the efficient utilization of solar energy to address the energy crisis and reduce environmental pollution. Cadmium sulfide (CdS)/graphite-type carbon nitride (g-C3N4) nanocomposites were synthesized using a hydrothermal method, and their photoelectrochemical properties and photocatalytic performance for hydrogen evolution reaction (HER) were characterized. Scanning electron microscope images showed the intimate interface and caviar-like nanoheterojunction of the CdS nanoparticles on g-C3N4 nanospheres, suggesting their potential involvement in the photocatalytic process. Electrochemical and spectroscopic analyses were conducted to confirm the roles of CdS in the nanoheterojunction. The results showed that 10 wt% CdS/g-C3N4 nanospheres exhibited higher photocatalytic activity than pure g-C3N4 under visible light irradiation. A HER rate of 655.5 mu mol/g/h was achieved after three photocatalytic cycles, signifying good photocatalytic stability. The synergistic effect of the Z-scheme heterojunction formed by g-C3N4 and CdS was identified as the main factor responsible for the enhanced photocatalytic performance and stability. The interface engineering effect of CdS/g-C3N4 facilitated the separation of photogenerated electrons and holes. This study provides insights into the design and fabrication of efficient HER photocatalysts.

Keyword:

CdS/g-C3N4 nanoheterojunctions hydrogen evolution reaction photocatalytic performance synergistic effect visible light

Community:

  • [ 1 ] [Niu, Yu]Sanming Univ, Sch Resources & Chem Engn, Sanming 365004, Peoples R China
  • [ 2 ] [Guo, Wenqin]Sanming Univ, Sch Resources & Chem Engn, Sanming 365004, Peoples R China
  • [ 3 ] [Zhu, Xiaoyan]Sanming Univ, Sch Resources & Chem Engn, Sanming 365004, Peoples R China
  • [ 4 ] [Guo, Lanlan]Sanming Univ, Sch Resources & Chem Engn, Sanming 365004, Peoples R China
  • [ 5 ] [Li, Fuying]Sanming Univ, Sch Resources & Chem Engn, Sanming 365004, Peoples R China
  • [ 6 ] [Niu, Yu]Krirk Univ, Int Coll, Dept Engn Technol Management, Bangkok 10220, Thailand
  • [ 7 ] [Li, Fuying]Krirk Univ, Int Coll, Dept Engn Technol Management, Bangkok 10220, Thailand
  • [ 8 ] [Shen, Jinni]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 9 ] [Wang, Yueqi]Fuzhou Univ, Fujian Univ Engn Res Ctr React Distillat Technol, Fuzhou 350007, Peoples R China

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Source :

MOLECULES

ISSN: 1420-3049

Year: 2023

Issue: 17

Volume: 28

4 . 2

JCR@2023

4 . 2 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 6

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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