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author:

Wang, Hengrui (Wang, Hengrui.) [1] | Jiang, Yue (Jiang, Yue.) [2] | Ma, Zhewen (Ma, Zhewen.) [3] | Shi, Yongqian (Shi, Yongqian.) [4] (Scholars:施永乾) | Zhu, Yanjun (Zhu, Yanjun.) [5] | Huang, Ruizhe (Huang, Ruizhe.) [6] | Feng, Yuezhan (Feng, Yuezhan.) [7] | Wang, Zubin (Wang, Zubin.) [8] | Hong, Min (Hong, Min.) [9] | Gao, Jiefeng (Gao, Jiefeng.) [10] | Tang, Long-Cheng (Tang, Long-Cheng.) [11] | Song, Pingan (Song, Pingan.) [12]

Indexed by:

EI Scopus SCIE

Abstract:

MXene aerogels have shown great potential for many important functional applications, in particular electromagnetic interference (EMI) shielding. However, it has been a grand challenge to create mechanically hyperelastic, air-stable, and durable MXene aerogels for enabling effective EMI protection at low concentrations due to the difficulties in achieving tailorable porous structures, excellent mechanical elasticity, and desired antioxidation capabilities of MXene in air. Here, a facile strategy for fabricating MXene composite aerogels by co-assembling MXene and cellulose nanofibers during freeze-drying followed by surface encapsulation with fire-retardant thermoplastic polyurethane (TPU) is reported. Because of the maximum utilization of pore structures of MXene, and conductive loss enhanced by multiple internal reflections, as-prepared aerogel with 3.14 wt% of MXene exhibits an exceptionally high EMI shielding effectiveness of 93.5 dB, and an ultra-high MXene utilization efficiency of 2977.71 dB g g-1, tripling the values in previous works. Owing to the presence of multiple hydrogen bonding and the TPU elastomer, the aerogel exhibits a hyperelastic feature with additional strength, excellent stability, superior durability, and high fire safety. This study provides a facile strategy for creating multifunctional aerogels with great potential for applications in EMI protection, wearable devices, thermal management, pressure sensing, and intelligent fire monitoring. Hyperelastic, robust, fire-safe multifunctional MXene aerogels with superior electromagnetic interference (EMI) shielding, thermal insulation, and air/moisture resistance are created by an encapsulation strategy. The MXene aerogel shows high EMI shielding effectiveness of 93.5 dB and ultra-high EMI utilization efficiency of MXene of 2977.71 dB g g-1, resulting from efficient utilization of pore structure and multiple internal reflections.image

Keyword:

electromagnetic interference shielding efficiency hyperelasticity mechanical robustness multifunction MXenes

Community:

  • [ 1 ] [Wang, Hengrui]Fuzhou Univ, Coll Environm & Safety Engn, 2 Xueyuan Rd, Fuzhou 350116, Peoples R China
  • [ 2 ] [Shi, Yongqian]Fuzhou Univ, Coll Environm & Safety Engn, 2 Xueyuan Rd, Fuzhou 350116, Peoples R China
  • [ 3 ] [Zhu, Yanjun]Fuzhou Univ, Coll Environm & Safety Engn, 2 Xueyuan Rd, Fuzhou 350116, Peoples R China
  • [ 4 ] [Huang, Ruizhe]Fuzhou Univ, Coll Environm & Safety Engn, 2 Xueyuan Rd, Fuzhou 350116, Peoples R China
  • [ 5 ] [Jiang, Yue]Jiaxing Univ, China Australia Inst Adv Mat & Mfg, Jiaxing 314001, Peoples R China
  • [ 6 ] [Ma, Zhewen]Tongji Univ, Sch Mat Sci & Engn, Dept Inorgan Mat, Shanghai 201804, Peoples R China
  • [ 7 ] [Feng, Yuezhan]Zhengzhou Univ, Natl Engn Res Ctr Adv Polymer Proc Technol, Key Lab Mat Proc & Mold, Minist Educ, Zhengzhou 450002, Peoples R China
  • [ 8 ] [Wang, Zubin]South China Univ Technol, Inst Safety Sci & Engn, Sch Mech & Automot Engn, Wushan Rd 381, Guangzhou 510641, Peoples R China
  • [ 9 ] [Hong, Min]Univ Southern Queensland, Ctr Future Mat, Springfield 4300, Australia
  • [ 10 ] [Song, Pingan]Univ Southern Queensland, Ctr Future Mat, Springfield 4300, Australia
  • [ 11 ] [Gao, Jiefeng]Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Peoples R China
  • [ 12 ] [Tang, Long-Cheng]Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Chem & Mat Technol MoE, Hangzhou 311121, Peoples R China
  • [ 13 ] [Song, Pingan]Univ Southern Queensland, Sch Agr & Environm Sci, Springfield 4300, Australia

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2023

Issue: 49

Volume: 33

1 8 . 5

JCR@2023

1 8 . 5 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 136

SCOPUS Cited Count: 130

ESI Highly Cited Papers on the List: 5 Unfold All

  • 2025-1
  • 2024-11
  • 2024-9
  • 2024-7
  • 2024-5

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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