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author:

Cheng, F.-F. (Cheng, F.-F..) [1] | Qin, S.-F. (Qin, S.-F..) [2] | You, L.-X. (You, L.-X..) [3] | Sun, J.-J. (Sun, J.-J..) [4]

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Abstract:

The hydrogen redox reaction is a fundamental aspect of electrochemical sciences. However, a thorough understanding of its kinetics in weak acids, both monobasic and multivariate, has yet to be established through directed investigations. In this study, we present evidence of diffusion-controlled kinetics of hydrogen redox reactions in HCOONa, NaH2PO4, and H8C6O7 solutions using polycrystalline Pt disk electrodes. The redox reactions in the HCOONa solutions go through two processes including H+ + e- ↔ 1/2H2 and HCOOH + e- ↔ 1/2H2 + HCOO- at lower pH (≤2.57) and HCOOH + e- ↔ 1/2H2 + HCOO- at pH values ranging from 2.57 to 4.70. The diffusion coefficients of HCOOH and HCOO- and standard heterogeneous rate constants (k0) are estimated to be (8.4 ± 0.8) × 10-6 cm2·s-1, (6.5 ± 0.4) × 10-6 cm2·s-1, and (5.9 ± 3.9) × 10-3 cm·s-1, respectively. In the NaH2PO4 solution, three main electrochemical steps are deduced as the electron exchange between the species HPO42-, H2PO4-, and H3PO4 and electrodes. The values of DH-, DHPO2-, and DH are found to be (4.1 ± 0.2) × 10-6, (4.3 ± 0.1) × 10-6, and (6.8 ± 0.3) × 10-6 cm2·s-1. Besides, multisteps and much more complex hydrogen redox reactions are observed in the H8C6O7 solutions. These findings based on electrochemically kinetic experimental data provide a universal framework for insights into understanding and interpretation of hydrogen redox processes relevant to water splitting, hydrogen generation, and storage. © 2023 American Chemical Society.

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  • [ 1 ] [Cheng F.-F.]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fujian province, Fuzhou, 350108, China
  • [ 2 ] [Qin S.-F.]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fujian province, Fuzhou, 350108, China
  • [ 3 ] [You L.-X.]College of Geography and Environmental Sciences, Zhejiang Normal University, Zhejiang Province, Jinhua, 321004, China
  • [ 4 ] [Sun J.-J.]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fujian province, Fuzhou, 350108, China

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Journal of Physical Chemistry C

ISSN: 1932-7447

Year: 2023

Issue: 39

Volume: 127

Page: 19415-19423

3 . 3

JCR@2023

3 . 3 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:3

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ESI Highly Cited Papers on the List: 0 Unfold All

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30 Days PV: 0

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