This　study　prepares　volcanic　ash　(VA)-blast　furnace　slag　(S)　based　alkali-activated　materials　(AAM)　with　the　addition　of　ceramic　waste　for　exposure　to　high　temperatures　(1000　degrees　C).　The　tem-perature　resistance　of　alkali-activated　materials　were　described　by　measuring　their　surface　mor-phology,　gel　structure　and　thermal　damage　degree,　through　NMR　and　UPV　tests.　At　calcination　temperature　of　800　degrees　C,　the　VA-based　alkali-activated　materials　with　ceramic　waste　shows　ultra-sonic　velocity　of　1962　m/s　and　a　porosity　of　17.30　%,　indicating　the　prevention　from　gel　struc-tural　collapse.　As　low　calcination　temperatures　(＜=　600　degrees　C),　ceramic　waste　only　functions　as　filler　materials　and　reduces　compressive　strength　of　the　alkali-activated　materials.　While　at　calcination　temperature　of　800　degrees　C,　there　is　an　activity　generated　by　the　transformation　of　crystalline　phases　into　amorphous　phases　in　the　ceramic　waste,　thus　participates　the　alkali-activated　reaction　and　increases　compressive　strength　of　the　alkali-activated　materials.　At　1000　degrees　C,　the　collapse　of　skele-ton　of　the　alkali-activated　material　is　induced　by　thermal　incompatibility　of　the　matrix　and　ther-mal　compression.