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author:

Xia, Li (Xia, Li.) [1] | Yan, Xiaolin (Yan, Xiaolin.) [2] | Zhang, Yinggan (Zhang, Yinggan.) [3] | Wu, Hualong (Wu, Hualong.) [4] | Zhang, Shiyu (Zhang, Shiyu.) [5] | Chang, Xiaoqing (Chang, Xiaoqing.) [6] | Sa, Baisheng (Sa, Baisheng.) [7] (Scholars:萨百晟) | Lin, Liang (Lin, Liang.) [8] | Luo, Qing (Luo, Qing.) [9] | Wang, Laisen (Wang, Laisen.) [10] | Peng, Dong-Liang (Peng, Dong-Liang.) [11] | Xie, Qingshui (Xie, Qingshui.) [12]

Indexed by:

EI Scopus SCIE

Abstract:

Lithium metal batteries (LMBs) are considered by most researchers as among the most prospective nextgeneration high energy density storage devices because of high theoretical capacity (3860 mAh g - 1) and low reduction potential (-3.040 V compared to standard hydrogen electrode) of Li metal anode. Nevertheless, the uncontrollable dendrite growth of the Li metal anode during cycling hinders the commercial application of LMBs. Herein, we put forward a hybrid protective layer containing LiZn alloy and LiI at the surface of the Li metal anode. Thanks to the "lithiophilic" feature of LiZn alloy and LiI having a low surface Li+ diffusion energy barrier, the constructed homogeneous hybrid protective layer can reduce the nucleation barrier and facilitate Li+ rapid diffusion. As a consequence, Li metal anode exhibits a smooth plating/stripping morphology and can suppress the dendrite formation. Notably, the constructed ZI@Li || ZI@Li symmetrical cell realizes stable cycling for 470 h at 2 mA cm-2 and 2 mAh cm-2, and LMBs matched with commercial LiFePO4 cathode deliver greatly enhanced electrochemical properties. This hybrid protective layer provides a feasible strategy to realize even plating/ stripping of Li metal, which would promote the high energy density LMBs for practical applications.

Keyword:

Highly stable Li metal anodes Homogeneous nucleation Li plus diffusion LiZn alloy

Community:

  • [ 1 ] [Xia, Li]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 2 ] [Yan, Xiaolin]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 3 ] [Zhang, Yinggan]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 4 ] [Wu, Hualong]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 5 ] [Zhang, Shiyu]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 6 ] [Chang, Xiaoqing]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 7 ] [Lin, Liang]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 8 ] [Luo, Qing]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 9 ] [Wang, Laisen]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 10 ] [Peng, Dong-Liang]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 11 ] [Xie, Qingshui]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 12 ] [Xie, Qingshui]Xiamen Univ, Shenzhen Res Inst, Shenzhen 518000, Peoples R China
  • [ 13 ] [Sa, Baisheng]Fuzhou Univ, Coll Mat Sci & Engn, Multiscale Computat Mat Facil, Fuzhou 350100, Peoples R China

Reprint 's Address:

  • [Lin, Liang]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China;;[Luo, Qing]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China;;[Xie, Qingshui]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surface, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China;;[Xie, Qingshui]Xiamen Univ, Shenzhen Res Inst, Shenzhen 518000, Peoples R China;;

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Source :

ELECTROCHIMICA ACTA

ISSN: 0013-4686

Year: 2023

Volume: 475

5 . 5

JCR@2023

5 . 5 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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