Metal-Free Heterogeneous Photocatalysis for Carbocarboxylation of Alkenes: Efficient Synthesis of γ-Amino Carboxylic Derivatives - Details

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Abstract：

A　metal-free　heterogeneous　protocol　is　established　herein　for　the　synthesis　of　value-added　γ-amino　acid　scaffolds　via　carbocarboxylation　of　alkenes　with　CO2　and　alkylamines　under　visible　light　irradiation.　The　protocol　shows　broad　substrate　scope　under　mild　reaction　conditions　and　good　stability　of　the　catalyst　for　recycle　tests.　Moreover,　the　methodology　could　be　feasible　to　the　late-stage　derivatization　of　several　natural　products,　enriching　the　chemical　arsenal　for　practical　application.　©　2024　Wiley-VCH　GmbH.

Keyword：

boron carbonitride carbon dioxide carboxylation metal-free photocatalysis γ-amino acids

Community：

[ 1 ] [Wu Z.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 2 ] [Zhai S.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 3 ] [Luo M.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 4 ] [Dong Q.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 5 ] [Wu S.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 6 ] [Zheng M.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 7 ] [Zheng M.]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University), College of Chemistry, Fuzhou, 350116, China

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Metal-Free Heterogeneous Photocatalysis for Carbocarboxylation of Alkenes: Efficient Synthesis of γ-Amino Carboxylic Derivatives
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Source ：

Chemistry - An Asian Journal

ISSN： 1861-4728

Year： 2024

Issue： 5

Volume： 19

3 . 5 0 0

JCR@2023

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SCOPUS Cited Count： 1

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 1

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