Metal-organic framework-based single-atom electro-/photocatalysts: Synthesis, energy applications, and opportunities - Details

author：

Indexed by：

EI CSCD

Abstract：

Single-atom　catalysts　(SACs)　have　gained　substantial　attention　because　of　their　exceptional　catalytic　properties.　However,　the　high　surface　energy　limits　their　synthesis,　thus　creating　significant　challenges　for　further　development.　In　the　last　few　years,　metal–organic　frameworks　(MOFs)　have　received　significant　consideration　as　ideal　candidates　for　synthesizing　SACs　due　to　their　tailorable　chemistry,　tunable　morphologies,　high　porosity,　and　chemical/thermal　stability.　From　this　perspective,　this　review　thoroughly　summarizes　the　previously　reported　methods　and　possible　future　approaches　for　constructing　MOF-based　(MOF-derived-supported　and　MOF-supported)　SACs.　Then,　MOF-based　SAC＇s　identification　techniques　are　briefly　assessed　to　understand　their　coordination　environments,　local　electronic　structures,　spatial　distributions,　and　catalytic/electrochemical　reaction　mechanisms.　This　review　systematically　highlights　several　photocatalytic　and　electrocatalytic　applications　of　MOF-based　SACs　for　energy　conversion　and　storage,　including　hydrogen　evolution　reactions,　oxygen　evolution　reactions,　O2/CO2/N2　reduction　reactions,　fuel　cells,　and　rechargeable　batteries.　Some　light　is　also　shed　on　the　future　development　of　this　highly　exciting　field　by　highlighting　the　advantages　and　limitations　of　MOF-based　SACs.　©　2023　The　Authors.　Carbon　Energy　published　by　Wenzhou　University　and　John　Wiley　&　Sons　Australia,　Ltd.

Keyword：

Atoms Carbon Chemical stability Coordination reactions Electronic structure Fuel cells Hydrogen storage Metal-Organic Frameworks Organic polymers

Community：

[ 1 ] [Ahmad, Munir]Shenzhen Key Laboratory of Energy Electrocatalytic Materials, Guangdong Research Center for Interfacial Engineering of Functional Materials, College of Materials Science and Engineering, Shenzhen University, Guangdong, Shenzhen, China
[ 2 ] [Ahmad, Munir]College of Physics and Optoelectronic Engineering, Shenzhen University, Guangdong, Shenzhen, China
[ 3 ] [Chen, Jiahui]Shenzhen Key Laboratory of Energy Electrocatalytic Materials, Guangdong Research Center for Interfacial Engineering of Functional Materials, College of Materials Science and Engineering, Shenzhen University, Guangdong, Shenzhen, China
[ 4 ] [Chen, Jiahui]College of Physics and Optoelectronic Engineering, Shenzhen University, Guangdong, Shenzhen, China
[ 5 ] [Liu, Jianwen]Shenzhen Key Laboratory of Energy Electrocatalytic Materials, Guangdong Research Center for Interfacial Engineering of Functional Materials, College of Materials Science and Engineering, Shenzhen University, Guangdong, Shenzhen, China
[ 6 ] [Zhang, Yan]Shenzhen Key Laboratory of Energy Electrocatalytic Materials, Guangdong Research Center for Interfacial Engineering of Functional Materials, College of Materials Science and Engineering, Shenzhen University, Guangdong, Shenzhen, China
[ 7 ] [Zhang, Yan]College of Physics and Optoelectronic Engineering, Shenzhen University, Guangdong, Shenzhen, China
[ 8 ] [Song, Zhongxin]College of Chemistry and Environmental Engineering, Shenzhen University, Guangdong, Shenzhen, China
[ 9 ] [Afzal, Shahzad]Department of Environmental Engineering, China Jiliang University, Zhejiang, Hangzhou, China
[ 10 ] [Raza, Waseem]Institute for Advanced Study, Shenzhen University, Guangdong, Shenzhen, China
[ 11 ] [Zeb, Liaqat]School of Bioengineering, Dalian University of Technology, Liaoning, Dalian, China
[ 12 ] [Mehmood, Andleeb]College of Physics and Optoelectronic Engineering, Shenzhen University, Guangdong, Shenzhen, China
[ 13 ] [Hussain, Arshad]Institute for Advanced Study, Shenzhen University, Guangdong, Shenzhen, China
[ 14 ] [Zhang, Jiujun]College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, China
[ 15 ] [Zhang, Jiujun]Institute for Sustainable Energy, Shanghai University, Shanghai, China
[ 16 ] [Fu, Xian-Zhu]Shenzhen Key Laboratory of Energy Electrocatalytic Materials, Guangdong Research Center for Interfacial Engineering of Functional Materials, College of Materials Science and Engineering, Shenzhen University, Guangdong, Shenzhen, China
[ 17 ] [Luo, Jing-Li]Shenzhen Key Laboratory of Energy Electrocatalytic Materials, Guangdong Research Center for Interfacial Engineering of Functional Materials, College of Materials Science and Engineering, Shenzhen University, Guangdong, Shenzhen, China

Reprint 's Address：

Email：

Show more details

Related Keywords：

Research Progress in Vehicular High Mass Density Solid Hydrogen Storage Materials
2022，Chinese Journal of Rare Metals
Heterogeneous Iridium Single-Atom Molecular-like Catalysis for Epoxidation of Ethylene
2023，Journal of the American Chemical Society
Effect of the chemisorbed molecular structure on the frequency of carbon nanotube resonators: Molecular dynamics simulations
2013，8th Annual IEEE International Conference on Nano/Micro Engineered and Molecular Systems, IEEE NEMS 2013
Thermodynamics analysis of Al-Ti-C-RE prepared by rare earth oxide Ce2O3
2013，Chinese Journal of Nonferrous Metals
Unveiling the microstructure and promising electrochemical performance of heavily phosphorus-doped diamond electrodes
2024，Electrochimica Acta

Source ：

Carbon Energy

Year： 2024

Issue： 1

Volume： 6

1 9 . 5 0 0

JCR@2023

CAS Journal Grade：1

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 20

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 3

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search Engineering Village

Type
Departments

All Years Choose Year From to