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Abstract:
All-inorganic perovskite quantum dots (PQDs) have excellent photoelectric performance, such as high photoluminescence quantum yield (PLQY), narrow full width at half-maximum (FWHM), and emission spectra covering the visible light wavelength. The emission color can be tuned over the full visible spectral region making them promising for white-light-emitting diodes (WLEDs). Further control over the optical and magnetic properties of PQDs can be achieved through doping of transition metal ions such asMn2C ions. In this paper, a rapid doping method is employed at room temperature by using strong-acid cation-exchange resin during the metal ions doping process, which shortens the doping time, and MnVCsPb.Cl=Br/3 QDs were obtained. By controlling the reaction time between strong-acid cation-exchange resin and PQDs,we achieve different levels of manganese doping, resulting in a new, to the best of our knowledge, fluorescence peak at 600 nm. The introduction of strong-acid cation-exchange resin preserves the integrity of thePQDstructure, while completing the doping within 30 min.Due to the low cost and mild reaction conditions of resin, it is expected that theMnVCsPb.Cl=Br/3 QDs can be mass-produced in large quantities. In addition, in order to provide high-quality white light emission, and prevent anion exchange reactions when mixed with CsPbBr3 QDs, the CsPbBr3 QDs are coated with silicon. Finally, by combining ultraviolet-lightemitting diodes (UVLEDs) with the aforementioned PQD mixture, this paper successfully fabricates WLEDs and demonstrates its excellent photoelectric performance. The constructed WLEDs produce warm white light with a high color rendering index (CRI) of 91 and a high correlated color temperature (CCT) of 5966 K, and the luminous efficacy (LE) ofWLEDsis 41 lmW-1. © 2024 Optica Publishing Group.
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Journal of the Optical Society of America B: Optical Physics
ISSN: 0740-3224
Year: 2024
Issue: 3
Volume: 41
Page: 809-819
1 . 8 0 0
JCR@2023
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