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author:

Song, Jianxin (Song, Jianxin.) [1] | Jiang, Lisha (Jiang, Lisha.) [2] | Wang, Xiaoze (Wang, Xiaoze.) [3] | Hou, Chuanxin (Hou, Chuanxin.) [4] | Wang, Xuemin (Wang, Xuemin.) [5] | Xu, Zijun (Xu, Zijun.) [6] | Liang, Chao (Liang, Chao.) [7] | Yuan, Mengnan (Yuan, Mengnan.) [8] | Tan, Chuan (Tan, Chuan.) [9] | Yang, Jing (Yang, Jing.) [10] | Song, Enhai (Song, Enhai.) [11] | Wang, Yanlong (Wang, Yanlong.) [12] | Liu, Wei (Liu, Wei.) [13]

Indexed by:

EI

Abstract:

Developing luminescent materials with suitable correlated color temperature (CCT) and sufficient color-rendering index (CRI) is a challenging problem in the field of commercialized warm white LED lighting. Herein, a novel metal-organic gel (MOG) material named YTU-G-1(SE) was synthesized, consisting of zirconium metal coordinated with 1,1,2,2-tetrakis(4-carboxyphenyl) ethylene. YTU-G-1(SE) exhibits strong fluorescent properties with an aggregation-induced emission (AIE) effect, emitting yellow-green fluorescence at 515 nm. The internal and external quantum efficiencies (IQE/EQE) of YTU-G-1(SE) are close to unity, with values of 95.74 ± 0.5% and 88.67 ± 0.5%, respectively. Finally, we combined YTU-G-1(SE) with a commercial blue chip and a commercial red phosphor (Sr,Ca)AlSiN3:Eu2+ to fabricate a warm white light LED with a color temperature of 3736 K, a color-rendering index Ra of 88.2, and a lumen efficiency of 79.42 lm W−1. This work provides a new approach to regulating the emission of AIE and offers a novel idea for developing high-performance warm-white pc-WLEDs. © 2024 The Royal Society of Chemistry

Keyword:

Color Efficiency Ethylene Fluorescence Light emitting diodes Organometallics Zirconium

Community:

  • [ 1 ] [Song, Jianxin]School of Environmental and Material Engineering, Yantai University, Shandong, Yantai; 264005, China
  • [ 2 ] [Jiang, Lisha]School of Environmental and Material Engineering, Yantai University, Shandong, Yantai; 264005, China
  • [ 3 ] [Wang, Xiaoze]MOE Key Laboratory for Analytical Science of Food Safety and Biology, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, China
  • [ 4 ] [Hou, Chuanxin]School of Environmental and Material Engineering, Yantai University, Shandong, Yantai; 264005, China
  • [ 5 ] [Wang, Xuemin]School of Environmental and Material Engineering, Yantai University, Shandong, Yantai; 264005, China
  • [ 6 ] [Xu, Zijun]School of Environmental and Material Engineering, Yantai University, Shandong, Yantai; 264005, China
  • [ 7 ] [Liang, Chao]School of Environmental and Material Engineering, Yantai University, Shandong, Yantai; 264005, China
  • [ 8 ] [Yuan, Mengnan]School of Civil Engineering, Yantai University, Yantai; 264005, China
  • [ 9 ] [Tan, Chuan]School of Environmental and Material Engineering, Yantai University, Shandong, Yantai; 264005, China
  • [ 10 ] [Yang, Jing]College of Chemical and Biological Engineering, Shandong University of Science and Technology, Shandong, Qingdao; 266590, China
  • [ 11 ] [Song, Enhai]State Key Laboratory of Luminescent Materials and Devices, Institute of Optical Communication Materials, South China University of Technology, Guangzhou; 510641, China
  • [ 12 ] [Wang, Yanlong]State Key Laboratory of Radiation Medicine and Protection, School for Radiological and interdisciplinary Sciences (RAD-X), Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, China
  • [ 13 ] [Liu, Wei]School of Environmental and Material Engineering, Yantai University, Shandong, Yantai; 264005, China

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Source :

Dalton Transactions

ISSN: 1477-9226

Year: 2024

Issue: 11

Volume: 53

Page: 4968-4975

3 . 5 0 0

JCR@2023

Cited Count:

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ESI Highly Cited Papers on the List: 0 Unfold All

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Chinese Cited Count:

30 Days PV: 0

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