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author:

Lin, Changgen (Lin, Changgen.) [1] | Zhang, Yongmei (Zhang, Yongmei.) [2] | Qian, Jiaqi (Qian, Jiaqi.) [3] | Chen, Zhiyi (Chen, Zhiyi.) [4] | Huang, Jiongyuan (Huang, Jiongyuan.) [5] | Ai, Na (Ai, Na.) [6] (Scholars:艾娜) | Jiang, San Ping (Jiang, San Ping.) [7] | Wang, Xin (Wang, Xin.) [8] (Scholars:王欣) | Shao, Yanqun (Shao, Yanqun.) [9] (Scholars:邵艳群) | Chen, Kongfa (Chen, Kongfa.) [10] (Scholars:陈孔发)

Indexed by:

EI Scopus SCIE

Abstract:

Perovskite oxide La0.9Sr0.1Ga0.8Mg0.2O3 (LSGM) is an intermedium-temperature solid oxide cell electrolyte material with extraordinary oxygen-ion conductivity. However, the manufacturing procedures of LSGM discs are complex involving multiple steps of powder preparation, forming, and sintering at high temperatures. Herein, thin LSGM electrolyte discs are prepared by coupling of tape casting and in situ solid-state reaction using oxides/carbonates as the feedstock. A pure-phase LSGM electrolyte disc with uniform elemental distribution is obtained by sintering at 1450 degrees C, and it possesses an ionic conductivity of 0.105 S cm(1) at 800 degrees C, a thermal expansion coefficient of 12.2 x 10(6) K-1, and a bending strength of 156 MPa A 170 mu m thick LSGM electrolyte-supported single cell delivers a peak power density of 0.96 W cm(2) at 800 degrees C and an electrolysis current density of 1.82 A cm(2) at 1.5 V with no noticeable degradation for 200 h. The findings of this research provide a cost-effective approach for manufacturing the LSGM electrolytes of efficient and durable solid oxide cells.

Keyword:

Electrolyte-support LSGM Solid oxide cells Solid-state reaction Tape casting

Community:

  • [ 1 ] [Lin, Changgen]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Zhang, Yongmei]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Qian, Jiaqi]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Chen, Zhiyi]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Huang, Jiongyuan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 6 ] [Wang, Xin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 7 ] [Shao, Yanqun]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 8 ] [Chen, Kongfa]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 9 ] [Ai, Na]Fuzhou Univ, Fujian Coll Assoc, Instrumental Anal Ctr, Fuzhou 350108, Fujian, Peoples R China
  • [ 10 ] [Jiang, San Ping]Natl Energy Key Lab New Hydrogen Ammonia Energy Te, Foshan 528200, Peoples R China
  • [ 11 ] [Jiang, San Ping]Foshan Xianhu Lab, Foshan 528200, Peoples R China
  • [ 12 ] [Jiang, San Ping]Curtin Univ, WA Sch Mines Minerals Energy & Chem Engn, Perth, WA 6102, Australia

Reprint 's Address:

  • 陈孔发

    [Chen, Kongfa]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China

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Source :

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY

ISSN: 0955-2219

Year: 2024

Issue: 6

Volume: 44

Page: 3818-3823

5 . 8 0 0

JCR@2023

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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