• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Lan, Jiajing (Lan, Jiajing.) [1] | Wang, Mengguang (Wang, Mengguang.) [2] | Lin, Qipu (Lin, Qipu.) [3] | Wang, Fei (Wang, Fei.) [4] | Chen, Shumei (Chen, Shumei.) [5] (Scholars:陈淑妹) | Zhang, Jian (Zhang, Jian.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

In this work, we synthesized two Cu-based heterometal-oxo clusters 1 and 2 based on M(III)(4)O-4 (M = Fe/In) cubane centers and obtained the corresponding dimers 3 and 4 by connecting Cu atoms on the cluster cores with the auxiliary ligand 4,4 '- bipyridine. They were characterized by single-crystal X-ray diffraction (SCXRD), powder X-ray diffraction (PXRD), and other tests. We conducted magnetic property study on compounds 1-4. The variable-temperature magnetic susceptibility test shows that compounds 1 and 3 exhibit significant ferromagnetic interactions at low temperatures, while compounds 2 and 4 exhibit overall antiferromagnetic interactions. When the metal at the cubane changes from magnetic Fe to nonmagnetic In, the magnetic interactions in the compound are weakened to a certain extent. Through dimerization, the extreme values of the variable-temperature magnetic susceptibility appear (1 to 3)/disappear (2 to 4) in the low-temperature section. We investigated the magnetic structure correlation of compounds 1-4 through bond lengths, bond angles, and distances between magnetic atoms. The results showed that compounds 1-4 exhibited significant magnetic coupling diversity.

Keyword:

Community:

  • [ 1 ] [Lan, Jiajing]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Wang, Mengguang]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Chen, Shumei]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Lan, Jiajing]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Wang, Mengguang]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Lin, Qipu]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Wang, Fei]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Zhang, Jian]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 陈淑妹

    [Chen, Shumei]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China;;[Wang, Fei]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

Show more details

Related Keywords:

Related Article:

Source :

CRYSTAL GROWTH & DESIGN

ISSN: 1528-7483

Year: 2024

Issue: 8

Volume: 24

Page: 3458-3466

3 . 2 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Online/Total:140/10033032
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1