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The nickel element doped holmium oxide (Ho2O3:Ni) transparent magneto-optical ceramics were fabricated by vacuum sintering and the dopant impacts on structure features and Faraday effects were investigated. The starting oxide powders were synthesized by pyrolyzing the resulting layered holmium-based hydroxide nanosheets prepared from a chemical precipitation route using the sodium hydroxide as precipitant at the freezing temperature. Upon high-temperature sintering, the Nii center dot center dot${\mathrm{Ni}}_i<^>{ \bullet \bullet }$ defect is introduced by Ni2+ substitution for Ho3+ to form the interstitial solid solution. The 1 at.% Ni2+ doped Ho2O3 ceramic sample exhibits an in-line transmittance of similar to 70.04% at 1 550 nm with a relative density of similar to 99.88%, while more Ni2+ incorporation (e.g., 2-5 at.%) even leads to a completely opaque state. The magneto-optical transparent Ho2O3:1%Ni ceramic developed in this work has Verdet constants of similar to-195, -65, and -29 rad/(T center dot m) at 635, 1 064, and 1 550 nm, respectively, which are similar to 1.8-fold higher than the commercial terbium gallium garnet crystal or similar to 1.4-fold higher than the pure Ho2O3 ceramic. This material also possesses relatively large figure of merit of similar to 14.6 degrees/T at 1 064 nm and relatively high thermal conductivity of similar to 7.5 W/(m center dot K) at room temperature. The magneto-optical transparent Ho2O3:xNi2+ (x = 1-5 at.%) ceramics were fabricated by vacuum sintering using layered rare-earth hydroxides as the precursors. Our results demonstrated that elemental nickel was a quite effective dopant for enhanced Verdet constant and the optimum ceramic composition of Ho2O3:1%Niexhibited good potential to apply to the high-power laser system, especially for use in the near-infrared region. image
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INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
ISSN: 1546-542X
Year: 2024
Issue: 3
Volume: 21
Page: 2510-2518
1 . 8 0 0
JCR@2023
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WoS CC Cited Count: 2
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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