The　ever-growing　demand　for　hydrogen　peroxide　(H2O2　)　makes　large-scale　production　via　environmentally-friendly　strategies　necessary.　The　electrochemical　oxygen　reduction　reaction　stands　out　as　an　efficient　and　green　approach　for　H2O2　production.　Here,　nitrogen-doped　mesoporous　carbon　materials　(NMCM)　with　a　hollow　semispherical　morphology　are　synthesized　for　H2O2　generation,　which　exhibit　remarkable　electrocatalytic　stability,　selectivity　(94.5%),　and　onset　potential　(similar　to　0.6　V)　toward　the　H2O2　formation　in　neutral　environment.　The　distinct　H2O2　production　performance　of　NMCM　can　be　attributed　to　synergistic　effect　of　two　factors,　that　is,　the　pyrrolic　N　to　optimize　the　work　function　and　the　hollow　semispherical　morphology　to　facilitate　mass　transfer　and　expose　abundant　electrocatalytic　active　sites.　This　work　offers　a　facile　way　to　prepare　metal-free　electrocatalysts　for　realizing　high-performance　H2O2　production　in　neutral　solutions.