Light-Controlled Cationic RAFT Polymerization of Vinyl Ethers Using N-Arylacridinium Photocatalysts - Details

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In　recent　years,　organophotocatalytic　polymerizations　have　received　significant　interest　as　they　enable　metal-free　and　highly　efficient　macromolecular　syntheses.　Herein,　we　disclose　the　development　of　N-arylacridinium　salts　as　an　effective　class　of　photocatalysts　that　could　mediate　the　cationic　reversible　addition-fragmentation　chain　transfer　(RAFT)　polymerization　of　vinyl　ethers　with　visible　light　regulation.　Owing　to　their　high　stability　and　matched　redox　potentials　with　trithiocarbonate　chain　transfer　agents,　N-arylacridinium　salts　are　capable　of　achieving　excellent　temporal　control　over　this　cationic　RAFT　polymerization　at　room　temperature　under　the　regulation　of　blue　and　green　light.　©　2024　American　Chemical　Society.

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[ 1 ] [Liu H.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Liu H.]Joint School of the National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou, 350207, China
[ 3 ] [Chen J.]State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China
[ 4 ] [Yang Z.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Yang Z.]State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China
[ 6 ] [Jiang L.]State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China
[ 7 ] [Liu W.]State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China
[ 8 ] [Ma J.-A.]Joint School of the National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou, 350207, China
[ 9 ] [Ma J.-A.]Department of Chemistry, Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Frontiers Science Center for Synthetic Biology, Ministry of Education, Tianjin Collaborative Innovation Centre of Chemical Science and Engineering, Tianjin University, Tianjin, 300072, China
[ 10 ] [Liao S.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Fuzhou University, Fuzhou, 350108, China
[ 11 ] [Liao S.]State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China

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Macromolecules

ISSN： 0024-9297

Year： 2024

Issue： 8

Volume： 57

Page： 3751-3756

5 . 1 0 0

JCR@2023

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