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Abstract:
Despite the high theoretical energy product and low material cost of Fe -rich 2:17 -type Sm-Co-Fe-CuZr magnets, it is still a big challenge to simultaneously achieve high energy product and high coercivity due to damaged cellular nanostructure, i.e. insufficient cell boundary precipitates. In this work, both high energy product ( -30.29 MGOe) and high coercivity ( -26.24 kOe) have been achieved in Fe -rich Sm 24.8 Co bal Fe 20.5 Cu 5.2 Zr x ( x wt%) magnets through optimizing Zr content. It reveals that raising Zr content from 1.5 wt% to 2.5 wt% can effectively refine the cellular nanostructure, which corresponds to an increased volume fraction of cell boundary precipitates. However, excess Zr content (e.g. above 2.5 wt%) leads to the formation of micron -sized Zr-rich Zr 6 Co 23 soft magnetic particles, weakening the hard magnetic performance. In particular, the high Zr-content (3.5 wt%) magnet exhibits strongly inhomogeneous chemistry as well as cellular nanostructure in the vicinity of micron -sized Zr 6 Co 23 particles (i.e. heterogeneous distribution of cell boundary precipitates), deteriorating both squareness factor and coercivity. As a result, the optimum magnetic property combination is achieved at an intermediate Zr concentration by balancing the contradictive effects between cell refinement and soft magnetic impurities. (c) 2024 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
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JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN: 1005-0302
CN: 21-1315/TG
Year: 2024
Volume: 193
Page: 178-186
1 1 . 2 0 0
JCR@2023
Cited Count:
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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