• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Wu, Liyun (Wu, Liyun.) [1] | Wu, Qilong (Wu, Qilong.) [2] | Han, Yun (Han, Yun.) [3] | Zhang, Dongdong (Zhang, Dongdong.) [4] | Zhang, Rongrong (Zhang, Rongrong.) [5] | Song, Nan (Song, Nan.) [6] | Wu, Xiaofeng (Wu, Xiaofeng.) [7] | Zeng, Jianrong (Zeng, Jianrong.) [8] | Yuan, Pei (Yuan, Pei.) [9] (Scholars:袁珮) | Chen, Jun (Chen, Jun.) [10] | Du, Aijun (Du, Aijun.) [11] | Huang, Keke (Huang, Keke.) [12] | Yao, Xiangdong (Yao, Xiangdong.) [13]

Indexed by:

EI Scopus SCIE

Abstract:

Defect-engineered bimetallic oxides exhibit high potential for the electrolysis of small organic molecules. However, the ambiguity in the relationship between the defect density and electrocatalytic performance makes it challenging to control the final products of multi-step multi-electron reactions in such electrocatalytic systems. In this study, controllable kinetics reduction is used to maximize the oxygen vacancy density of a CuCo oxide nanosheet (CuCo2O4 NS), which is used to catalyze the glycerol electrooxidation reaction (GOR). The CuCo2O4-x NS with the highest oxygen-vacancy density (CuCo2O4-x-2) oxidizes C3 molecules to C1 molecules with selectivity of almost 100% and a Faradaic efficiency of approximate to 99%, showing the best oxidation performance among all the modified catalysts. Systems with multiple oxygen vacancies in close proximity to each other synergistically facilitate the cleavage of CC bonds. Density functional theory calculations confirm the ability of closely spaced oxygen vacancies to facilitate charge transfer between the catalyst and several key glycolic-acid (GCA) intermediates of the GOR process, thereby facilitating the decomposition of C2 intermediates to C1 molecules. This study reveals qualitatively in tuning the density of oxygen vacancies for altering the reaction pathway of GOR by the synergistic effects of spatial proximity of high-density oxygen vacancies. In this work, the qualitative tuning of oxygen-vacancy density on the reaction pathway of glycerol electrooxidation (GOR) is investigated, demonstrating that the synergistic effect induced by neighboring oxygen vacancies effectively promotes the CC bond cleavage of C2 intermediates to formate. This work offers insights for designing high-performance GOR electrocatalysts, facilitating the development of cost-effective and energy-saving chemical production technologies. image

Keyword:

defect density glycerol oxidation reaction nitrobenzene reduction reaction oxygen vacancy synergistic effect

Community:

  • [ 1 ] [Wu, Liyun]Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
  • [ 2 ] [Zhang, Dongdong]Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
  • [ 3 ] [Zhang, Rongrong]Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
  • [ 4 ] [Song, Nan]Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
  • [ 5 ] [Huang, Keke]Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
  • [ 6 ] [Yao, Xiangdong]Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
  • [ 7 ] [Wu, Qilong]Univ Wollongong, Intelligent Polymer Res Inst, Australian Inst Innovat Mat, Wollongong, NSW 2500, Australia
  • [ 8 ] [Chen, Jun]Univ Wollongong, Intelligent Polymer Res Inst, Australian Inst Innovat Mat, Wollongong, NSW 2500, Australia
  • [ 9 ] [Wu, Qilong]Univ Wollongong, Australian Inst Innovat Mat, ARC Ctr Excellence Electromat Sci, Wollongong, NSW 2500, Australia
  • [ 10 ] [Chen, Jun]Univ Wollongong, Australian Inst Innovat Mat, ARC Ctr Excellence Electromat Sci, Wollongong, NSW 2500, Australia
  • [ 11 ] [Han, Yun]Griffith Univ, Queensland Micro & Nanotechnol Ctr, Sch Engn & Built Environm, Nathan Campus, Qld 4111, Australia
  • [ 12 ] [Wu, Xiaofeng]Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
  • [ 13 ] [Zeng, Jianrong]Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
  • [ 14 ] [Zeng, Jianrong]Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
  • [ 15 ] [Yuan, Pei]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350002, Peoples R China
  • [ 16 ] [Du, Aijun]Queensland Univ Technol, Sch Chem & Phys, Gardens Point Campus, Brisbane 4001, Australia
  • [ 17 ] [Du, Aijun]Queensland Univ Technol, Ctr Mat Sci, Gardens Point Campus, Brisbane 4001, Australia
  • [ 18 ] [Yao, Xiangdong]Sun Yat Sen Univ Shenzhen, Sch Adv Energy, Shenzhen 518107, Guangdong, Peoples R China
  • [ 19 ] [Yao, Xiangdong]Sun Yat Sen Univ Shenzhen, IGCME, Shenzhen 518107, Guangdong, Peoples R China

Reprint 's Address:

  • [Yao, Xiangdong]Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China;;[Yao, Xiangdong]Sun Yat Sen Univ Shenzhen, Sch Adv Energy, Shenzhen 518107, Guangdong, Peoples R China;;[Yao, Xiangdong]Sun Yat Sen Univ Shenzhen, IGCME, Shenzhen 518107, Guangdong, Peoples R China

Show more details

Related Keywords:

Source :

ADVANCED MATERIALS

ISSN: 0935-9648

Year: 2024

Issue: 26

Volume: 36

2 7 . 4 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

Online/Total:186/10019435
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1