Login | Cas Login
English| 简体中文| 繁体中文

  • Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

Advanced Search

author：

Liu, L. (Liu, L..) [1] | Liao, A. (Liao, A..) [2] | Lin, L. (Lin, L..) [3] | Huang, Y. (Huang, Y..) [4] | Zhang, Y. (Zhang, Y..) [5] | Liu, Y. (Liu, Y..) [6] | Gao, G. (Gao, G..) [7] | Lin, J. (Lin, J..) [8] | Sa, B. (Sa, B..) [9] | Wang, L. (Wang, L..) [10] | Peng, D.-L. (Peng, D.-L..) [11] | Xie, Q. (Xie, Q..) [12]

Indexed by：

Scopus

Abstract：

The　commercialization　of　Li–S　batteries　is　severely　hampered　by　the　electrically　insulated　nature　of　S　and　the　discharge　product　Li2S,　the　shuttle　effect　of　lithium　polysulfides　(LiPSs),　and　the　slow　redox　kinetics　between　Li2S2/Li2S.　Herein,　a　composite　of　Co–Ni　bimetallic　selenide　nanoparticles　embedded　in　honeycomb　porous　carbon　(Co–Ni–Se@C)　is　prepared　and　used　as　a　multifunctional　interlayer　on　the　separator　to　solve　the　above-mentioned　challenges　in　Li–S　batteries.　The　Co–Ni–Se@C　composite　with　high　electrical　conductivity　can　not　only　accelerate　Li+　and　electronic　transfer　but　also　have　good　chemisorption　and　catalytic　activity　for　LiPSs,　which　can　maximize　the　utilization　of　sulfur　active　material.　As　expected,　Li–S　batteries　assembled　with　Co–Ni–Se@C-PP　separator　exhibit　excellent　electrochemical　performance,　including　high　initial　discharge　capacity　of　1245　mAh　g−1　at　0.2　C,　superior　long　cycling　stability　with　a　0.066　%　decay　per　cycle　at　1.0　C,　and　an　excellent　rate　capacity　of　674　mAh　g−1　at　5.0　C.　In　addition,　a　satisfactory　capacity　of　1174　mAh　g−1　is　achieved　with　a　high　sulfur　loading　of　3.7　mAh　g−1　and　a　low　E/S　ratio　of　10　μL　mg−1.　This　work　provides　a　new　insight　into　the　application　of　bimetallic　selenides　in　high-performance　Li–S　batteries.　©　2024　Elsevier　B.V.

Keyword：

Bimetallic selenide Electrochemical properties Lithium-sulfur batteries Separator modification

Community：

  • [ 1 ] [Liu L.]State Key Laboratory for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials (Xiamen University), College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 2 ] [Liao A.]State Key Laboratory for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials (Xiamen University), College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 3 ] [Lin L.]State Key Laboratory for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials (Xiamen University), College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 4 ] [Huang Y.]State Key Laboratory for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials (Xiamen University), College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 5 ] [Zhang Y.]State Key Laboratory for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials (Xiamen University), College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 6 ] [Liu Y.]State Key Laboratory for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials (Xiamen University), College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 7 ] [Gao G.]State Key Laboratory for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials (Xiamen University), College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 8 ] [Lin J.]State Key Laboratory for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials (Xiamen University), College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 9 ] [Sa B.]Multiscale Computational Materials Facility, College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350100, China
  • [ 10 ] [Wang L.]State Key Laboratory for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials (Xiamen University), College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 11 ] [Peng D.-L.]State Key Laboratory for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials (Xiamen University), College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 12 ] [Xie Q.]State Key Laboratory for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials (Xiamen University), College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 13 ] [Xie Q.]Shenzhen Research Institute of Xiamen University, Shenzhen, 518000, China

Reprint 's Address：

Email：

Show more details

Related Keywords：

Related Article：

Source ：

Journal of Power Sources

ISSN： 0378-7753

Year： 2024

Volume： 608

8 . 1 0 0

JCR@2023

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 1

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS
Online/Total：205/9999646
Address：FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code：350116) Contact Us：0591-22865326
Copyright：FZU Library Technical Support：Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1