Photoswitched Stereodivergent Synthesis of Allylic Sulfones - Details

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The　present　Letter　demonstrates　a　photoswitched　stereodivergent　synthesis　of　allylic　sulfones　from　sodium　sulfinates,　triphenylvinylphosphonium　chloride,　and　(hetero)aromatic　aldehydes　in　a　single　step.　Mechanistically,　cis-allylic　sulfones,　generated　from　the　unstabilized　ylide　intermediates　and　aldehydes　in　situ,　could　be　finally　converted　to　trans-allylic　sulfones　via　photochemical　isomerization　in　the　presence　of　a　catalytic　amount　of　bis(2-thienyl)　ketone.　©　2024　American　Chemical　Society.

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[ 1 ] [Huang H.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Huang H.]Qingyuan Innovation Laboratory, Quanzhou, 362801, China
[ 3 ] [Xu L.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 4 ] [Xu L.]Qingyuan Innovation Laboratory, Quanzhou, 362801, China
[ 5 ] [Zhang C.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 6 ] [Zhang C.]Qingyuan Innovation Laboratory, Quanzhou, 362801, China
[ 7 ] [Cheng C.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 8 ] [Cheng C.]Qingyuan Innovation Laboratory, Quanzhou, 362801, China
[ 9 ] [Chai Z.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 10 ] [Yan H.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 11 ] [Yan H.]Qingyuan Innovation Laboratory, Quanzhou, 362801, China
[ 12 ] [Yan H.]State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361005, China
[ 13 ] [Chen F.-E.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 14 ] [Chen F.-E.]Qingyuan Innovation Laboratory, Quanzhou, 362801, China
[ 15 ] [Chen F.-E.]Engineering Center of Catalysis and Synthesis for Chiral Molecules, Department of Chemistry, Fudan University, Shanghai, 200433, China

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Organic Letters

ISSN： 1523-7060

Year： 2024

Issue： 23

Volume： 26

Page： 4916-4920

4 . 9 0 0

JCR@2023

CAS Journal Grade：1

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