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Magnesium-ion batteries are promising candidates for the next-generation energy storage systems. However, their development is restricted by the shortage of advanced insertion-type positive electrodes. Hybrid-ion batteries, which combine the facile alkali metal ions extraction/insertion of the cathode with the low-cost and high-safety magnesium metal anode, can harness the individual benefits of both electrodes and achieve satisfactory electrochemical performance. We present a high-performance magnesium-potassium hybrid ion battery utilizing a magnesium-potassium hybrid ion electrolyte, a magnesium metal anode, and a Prussian blue analogue cathode. The battery exhibits a discharge voltage of up to 3.0 V and delivers a reversible specific capacity of 120 mAh/g, resulting in an impressive energy density of 360 Wh/kg (based on the cathode mass only). Moreover, the battery demonstrates exceptional cycling stability, maintaining a capacity retention rate of 96% after 500 charge–discharge cycles at a current density of 50 mA/g. The reaction mechanism and energy storage mechanism of the hybrid ion battery were studied using various electrochemical testing methods and X-ray diffraction analysis. This work may provide new ideas and inspire the effort for the advancement of superior magnesium hybrid ion batteries. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.
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Ionics
ISSN: 0947-7047
Year: 2024
Issue: 7
Volume: 30
Page: 4055-4062
2 . 4 0 0
JCR@2023
CAS Journal Grade:4
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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