The synthesis and application of o-carborane-based macrocyclic arenes - Details

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Liu, J. (Liu, J..) ^[1] | Fu, M. (Fu, M..) ^[2] | Yuan, S. (Yuan, S..) ^[3] | Lin, C. (Lin, C..) ^[4] | Yuan, Y. (Yuan, Y..) ^[5]

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Abstract：

Two　o-carborane-hybridized　macrocyclic　arenes　have　been　synthesized　via　Friedel-Crafts　alkylation　of　carborane　diaryl　derivatives.　The　single-crystal　X-ray　diffraction　analysis　clearly　revealed　their　cavity　structure　and　intermolecular　interaction　force.　These　novel　macrocycles　exhibited　aggregation-induced　luminescence　and　intramolecular　charge　transfer　properties　and　also　significant　selectivity　towards　nitro　explosive　compounds.　This　work　provided　a　method　for　the　synthesis　of　hybridized　macrocyclic　arenes.　©　2024　The　Royal　Society　of　Chemistry

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[ 1 ] [Liu J.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Fu M.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [Yuan S.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 4 ] [Lin C.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Yuan Y.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Department of Chemistry, Fuzhou University, Fuzhou, 350108, China

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Dalton Transactions

ISSN： 1477-9226

Year： 2024

Issue： 36

Volume： 53

Page： 15316-15323

3 . 5 0 0

JCR@2023

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