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author:

Li, Ke-Xian (Li, Ke-Xian.) [1] | Li, Cai-Hong (Li, Cai-Hong.) [2] | Shi, Hao-Yan (Shi, Hao-Yan.) [3] | Chen, Rui (Chen, Rui.) [4] | She, Ao-Sheng (She, Ao-Sheng.) [5] | Yang, Yang (Yang, Yang.) [6] | Jiang, Xia (Jiang, Xia.) [7] | Chen, Yan-Xin (Chen, Yan-Xin.) [8] | Lu, Can-Zhong (Lu, Can-Zhong.) [9]

Indexed by:

Scopus SCIE

Abstract:

This study details the rational design and synthesis of Cu2ZnSnS4 (CZTS)-doped anatase (A) heterostructures, utilizing earth-abundant elements to enhance the efficiency of solar-driven water splitting. A one-step hydrothermal method was employed to fabricate a series of CZTS-A heterojunctions. As the concentration of titanium dioxide (TiO2) varied, the morphology of CZTS shifted from floral patterns to sheet-like structures. The resulting CZTS-A heterostructures underwent comprehensive characterization through photoelectrochemical response assessments, optical measurements, and electrochemical impedance spectroscopy analyses. Detailed photoelectrochemical (PEC) investigations demonstrated notable enhancements in photocurrent density and incident photon-to-electron conversion efficiency (IPCE). Compared to pure anatase electrodes, the optimized CZTS-A heterostructures exhibited a seven-fold increase in photocurrent density and reached a hydrogen production efficiency of 1.1%. Additionally, the maximum H-2 production rate from these heterostructures was 11-times greater than that of pure anatase and 250-times higher than the original CZTS after 2 h of irradiation. These results underscore the enhanced PEC performance of CZTS-A heterostructures, highlighting their potential as highly efficient materials for solar water splitting. Integrating Cu2ZnSnS4 nanoparticles (NPs) within TiO2 (anatase) heterostructures implied new avenues for developing earth-abundant and cost-effective photocatalytic systems for renewable energy applications.

Keyword:

copper-based sulfides Cu2ZnSnS4-anatase nanocomposite heterojunction photocatalytic H-2 generation

Community:

  • [ 1 ] [Li, Ke-Xian]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 2 ] [Li, Cai-Hong]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 3 ] [Shi, Hao-Yan]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 4 ] [Chen, Rui]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 5 ] [She, Ao-Sheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 6 ] [Yang, Yang]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 7 ] [Jiang, Xia]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 8 ] [Chen, Yan-Xin]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 9 ] [Lu, Can-Zhong]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 10 ] [Li, Ke-Xian]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350108, Peoples R China
  • [ 11 ] [Yang, Yang]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350108, Peoples R China
  • [ 12 ] [Chen, Yan-Xin]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350108, Peoples R China
  • [ 13 ] [Lu, Can-Zhong]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350108, Peoples R China
  • [ 14 ] [Li, Ke-Xian]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 15 ] [Li, Cai-Hong]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 16 ] [Shi, Hao-Yan]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 17 ] [Chen, Rui]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 18 ] [She, Ao-Sheng]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 19 ] [Yang, Yang]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 20 ] [Jiang, Xia]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 21 ] [Chen, Yan-Xin]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 22 ] [Lu, Can-Zhong]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 23 ] [Li, Cai-Hong]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • [Chen, Yan-Xin]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China;;[Lu, Can-Zhong]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China;;[Chen, Yan-Xin]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350108, Peoples R China;;[Lu, Can-Zhong]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350108, Peoples R China;;[Chen, Yan-Xin]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China;;[Lu, Can-Zhong]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China;;

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Source :

MOLECULES

Year: 2024

Issue: 11

Volume: 29

4 . 2 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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