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author:

Li, B. (Li, B..) [1] | Zhang, W. (Zhang, W..) [2] | Yang, K. (Yang, K..) [3] | Li, L. (Li, L..) [4] | Luo, J. (Luo, J..) [5] | Lin, Q. (Lin, Q..) [6] | Li, Y. (Li, Y..) [7] | Liu, Z. (Liu, Z..) [8] | Yu, Y. (Yu, Y..) [10] | Yang, C. (Yang, C..) [11]

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Abstract:

Studying lithium growth on diverse substrates with unique crystal structures is crucial for linking atomic and macroscopic views, which ensures a long cycle life and safety in lithium metal batteries. This work provides explanations on (1) the stages of nucleation, which are influenced by the adsorption-relaxation mechanism, (2) acquiring evolved traits of dendritic morphology from the embryo, and (3) the integration of the atomic and macroscopic perspectives through a variety of techniques at different scales to validate dendrite evolution. The heteroepitaxial growth process of the embryos is divided into two principal stages: nucleation and growth. The adsorption-type substrates exhibit characteristics of relatively lower average interaction energy and specific stress energy during the nucleation stage. At the growth stage, the adsorption-type substrate tends to facilitate multilayer growth. This work provides potential to design and material selection for lithium metal batteries, contributing to the development of safer, more efficient, and longer-lasting energy storage systems. © 2024 American Chemical Society.

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  • [ 1 ] [Li B.]Key Laboratory of Advanced Materials Technologies, International (Hong Kong Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies, College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 2 ] [Zhang W.]Key Laboratory of Advanced Materials Technologies, International (Hong Kong Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies, College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 3 ] [Yang K.]Key Laboratory of Advanced Materials Technologies, International (Hong Kong Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies, College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 4 ] [Li L.]Key Laboratory of Advanced Materials Technologies, International (Hong Kong Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies, College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 5 ] [Luo J.]Key Laboratory of Advanced Materials Technologies, International (Hong Kong Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies, College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 6 ] [Lin Q.]Key Laboratory of Advanced Materials Technologies, International (Hong Kong Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies, College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 7 ] [Li Y.]Key Laboratory of Advanced Materials Technologies, International (Hong Kong Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies, College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 8 ] [Liu Z.]Key Laboratory of Advanced Materials Technologies, International (Hong Kong Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies, College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 9 ] [Li L.]Key Laboratory of Advanced Materials Technologies, International (Hong Kong Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies, College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 10 ] [Yu Y.]Key Laboratory of Advanced Materials Technologies, International (Hong Kong Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies, College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 11 ] [Yang C.]Key Laboratory of Advanced Materials Technologies, International (Hong Kong Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies, College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China

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Source :

ACS Energy Letters

ISSN: 2380-8195

Year: 2024

Issue: 10

Volume: 9

Page: 5215-5224

1 9 . 5 0 0

JCR@2023

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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