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author:

Xia, Jun (Xia, Jun.) [1] | Liu, Haoyu (Liu, Haoyu.) [2] | Chen, Hang (Chen, Hang.) [3] | Chi, Xiaopeng (Chi, Xiaopeng.) [4] (Scholars:迟晓鹏) | Weng, Wei (Weng, Wei.) [5] (Scholars:翁威) | Zhong, Shuiping (Zhong, Shuiping.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

High-efficiency reduction of Fe3O4 particles in molten copper slag is the key for recovering slag-entrained copper, although restrained by the sluggish reaction kinetics of commercial powdery reductants with low density. Here, a new strategy by density tuning in conjunction with pelletizing of the powdery reductants is suggested, greatly enhancing the Fe3O4 reduction kinetics and resulting in remarkably facilitating the recovery of slag-entrained copper. Specifically, by replacing the industrially used coal powder with FeS2-C pellets at optimized density, the efficiency of Fe3O4 reduction is significantly increased from 18% to 51%, with the copper content in the low-layer slag being correspondingly enriched from 1.37% to 4.53%. The SEM-EDS characterizations and finite element analytical results all reveal that the enhanced reduction of Fe3O4 by the as-designed reductant contributes to the decrease of slag viscosity and copper exposure, as well as to the size growth of copper matte droplets, resulting in promoted settling of copper-containing components for copper-slag separation in the molten state. Additionally, the full exposure and size growth of copper matte in the molten state facilitate copper reclamation during the subsequent grinding-flotation process of the solidified slag, which increases the copper recovery from 23.3% to 85.3%, with the concentrate grade being correspondingly improved from 2.8% to 6.45% after one-stage flotation. The results can provide new insights into enhancing the recovery of slag-entrained copper.

Keyword:

Community:

  • [ 1 ] [Xia, Jun]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Liu, Haoyu]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 3 ] [Chi, Xiaopeng]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 4 ] [Weng, Wei]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 5 ] [Zhong, Shuiping]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 6 ] [Chi, Xiaopeng]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utilizat, Fuzhou 350108, Peoples R China
  • [ 7 ] [Weng, Wei]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utilizat, Fuzhou 350108, Peoples R China
  • [ 8 ] [Zhong, Shuiping]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utilizat, Fuzhou 350108, Peoples R China
  • [ 9 ] [Chen, Hang]Zijin Min Grp Co Ltd, Longyan 364200, Peoples R China
  • [ 10 ] [Zhong, Shuiping]Zijin Min Grp Co Ltd, Longyan 364200, Peoples R China

Reprint 's Address:

  • [Weng, Wei]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China;;[Zhong, Shuiping]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China;;[Weng, Wei]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utilizat, Fuzhou 350108, Peoples R China;;[Zhong, Shuiping]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utilizat, Fuzhou 350108, Peoples R China;;[Zhong, Shuiping]Zijin Min Grp Co Ltd, Longyan 364200, Peoples R China;;

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Source :

JOM

ISSN: 1047-4838

Year: 2024

Issue: 9

Volume: 76

Page: 4837-4848

2 . 1 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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