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The shortages of river sand and freshwater in marine engineering can be addressed by utilizing seawater and sea sand concrete (SWSSC). However, the sulfate resistance of SWSSC at low temperature is not clear. In this study, the seawater and sea sand cement mortar (SSCM) and ordinary cement mortar (OCM) with different limestone powder (LP) content were corroded by different sulfate solutions at 5 degrees C. The change of compressive strength and compositions of corrosion products in mortars after different times of corrosion were studied. The results show that SSCM presents 9.4 similar to 19 % lower strength loss and better sulfate resistance than OCM. The presence of Friedel's salt in SSCM contributes to a reduction in corrosion products like ettringite, gypsum, and thaumasite, thereby minimizing microstructural damage and mitigating the thaumasite sulfate attack (TSA). All mortars containing LP suffer from TSA and significantly damage with 17.4 similar to 48.7 % strength loss after 360 days of MgSO4 or Na2SO4 corrosion. Increasing the LP content exacerbates the TSA damage in SSCM. This is primarily due to the additional soluble carbonate from LP promoting the formation of gypsum and thaumasite, thereby worsening the microstructure deterioration of SSCM. Meanwhile, the thaumasite is not found in SSCM without LP after corrosion. In contrast to Na2SO4 corrosion, the thaumasite formation under MgSO4 corrosion mainly results from indirect reaction. The combined corrosion effects of Mg2+ and SO42- lead to a more significant increase in expansive products (thaumasite and gypsum) and TSA damage. The findings of this study help to advance the sulfate resistance of SWSSC in marine environments.
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CONSTRUCTION AND BUILDING MATERIALS
ISSN: 0950-0618
Year: 2024
Volume: 437
7 . 4 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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