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author:

Zhang, Xiaocheng (Zhang, Xiaocheng.) [1] | Yang, Rumeng (Yang, Rumeng.) [2] | Dong, Yu (Dong, Yu.) [3] | Zhang, Chuang (Zhang, Chuang.) [4] | Feng, Shiyu (Feng, Shiyu.) [5] | Huang, Weiguo (Huang, Weiguo.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

The booming demand on data security has aroused great interest for developing smart materials with temporal display feature and dynamic multicolor fluorescence. However, it remains challenging to implement both features on most responsive molecules. Herein, we construct a polymer free volume-controlled "molecular clock and emitter" via covalently embedding a multi-stimuli responsive molecular switch (i.e., spiropyran) into a polymer network (i.e., poly(pentafluorophenyl acrylate)) with programmable crosslink density and free volume. By the aminolysis of pentafluorophenyl ester with different amount of diamine crosslinkers, pPFPA-co-SP networks with controllable crosslink densities are generated, which have different confinement effects on the rate constant of SP/MC isomerization, thus leading to time-dependent photochromism. In addition, PTF1, a fluorescent probe that is sensitive to polymer rigidity, is introduced to further endow pPFPA-co-SP system with phototunable dynamic full-color emission. Therefore, relying on their synergistical responses to the rigidity of the polymer network, we have successfully developed a versatile molecular clock and emitter via an "one stone two birds" manner, which shows time-dependent data display along with dynamic multicolor fluorescence switching, providing great potential for advanced encryption and anticounterfeiting with a high security level. A versatile molecular clock and emitter consisting of pPFPA-co-SP and PTF1 has been developed via an "one stone (rigidity) two birds (clock and emitter)" strategy. Combining the synergistical responses of both pPFPA-co-SP and PTF1 toward the rigidity change of polymer network enables transient data display along with dynamic multicolor fluorescence switching, providing great potential for innovative applications from data security to display. image

Keyword:

dynamic anticounterfeiting full-color emission photo-switch rigidity-controlled color and emission transient information display

Community:

  • [ 1 ] [Zhang, Xiaocheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, 155 Yangqiao West Rd, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Yang, Rumeng]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, 155 Yangqiao West Rd, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Dong, Yu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, 155 Yangqiao West Rd, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Zhang, Chuang]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, 155 Yangqiao West Rd, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Feng, Shiyu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, 155 Yangqiao West Rd, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Huang, Weiguo]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, 155 Yangqiao West Rd, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Zhang, Xiaocheng]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 8 ] [Yang, Rumeng]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 9 ] [Zhang, Chuang]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 10 ] [Zhang, Xiaocheng]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 11 ] [Yang, Rumeng]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 12 ] [Zhang, Chuang]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 13 ] [Feng, Shiyu]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 14 ] [Huang, Weiguo]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 15 ] [Dong, Yu]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 16 ] [Feng, Shiyu]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 17 ] [Huang, Weiguo]Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Reprint 's Address:

  • [Feng, Shiyu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, 155 Yangqiao West Rd, Fuzhou 350002, Fujian, Peoples R China;;[Huang, Weiguo]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, 155 Yangqiao West Rd, Fuzhou 350002, Fujian, Peoples R China;;[Feng, Shiyu]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China;;[Huang, Weiguo]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China;;[Feng, Shiyu]Univ Chinese Acad Sci, Beijing 100049, Peoples R China;;[Huang, Weiguo]Univ Chinese Acad Sci, Beijing 100049, Peoples R China;;

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Source :

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ISSN: 1433-7851

Year: 2024

Issue: 38

Volume: 63

1 6 . 1 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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